Statistical associating fluid theory (SAFT) [1][2] is a chemical theory, based on perturbation theory, that uses statistical thermodynamics to explain how complex fluids and fluid mixtures form associations through hydrogen bonds.[3] Widely used in industry and academia, it has become a standard approach for describing complex mixtures.[4][5][6][7] Since it was first proposed in 1990, SAFT has been used in a large number of molecular-based equation of state[8][9] models for describing the Helmholtz energy contribution due to association.
^Chapman, W.G.; Gubbins, K.E.; Jackson, G.; Radosz, M. (December 1989). "SAFT: Equation-of-state solution model for associating fluids". Fluid Phase Equilibria. 52: 31–38. doi:10.1016/0378-3812(89)80308-5. S2CID 53310898.
^Cite error: The named reference ChapmanGubbinsJackson1990 was invoked but never defined (see the help page).
^Kontogeorgis, Georgios M.; Folas, Georgios K. (2010). "The Statistical Associating Fluid Theory (SAFT)". Thermodynamic Models for Industrial Applications. John Wiley & Sons, Ltd. pp. 221–259. doi:10.1002/9780470747537.ch8. ISBN 9780470747537.
^Müller, Erich; Gubbins, Keith (2001). "Molecular-Based Equations of State for Associating Fluids: A Review of SAFT and Related Approaches". Industrial & Engineering Chemistry Research. 40 (10): 2193–2211. doi:10.1021/ie000773w.
^Economou, Ioannis G. (4 October 2001). "Statistical Associating Fluid Theory: A Successful Model for the Calculation of Thermodynamic and Phase Equilibrium Properties of Complex Fluid Mixtures". Industrial & Engineering Chemistry Research. 41 (5): 953–962. doi:10.1021/ie0102201. eISSN 1520-5045. ISSN 0888-5885.
^Huang, Stanley H.; Radosz, Maciej (November 1990). "Equation of state for small, large, polydisperse, and associating molecules". Industrial & Engineering Chemistry Research. 29 (11): 2284–2294. doi:10.1021/ie00107a014. eISSN 1520-5045. ISSN 0888-5885.
^Tan, Sugata P.; Adidharma, Hertanto; Radosz, Maciej (2008-11-05). "Recent Advances and Applications of Statistical Associating Fluid Theory". Industrial & Engineering Chemistry Research. 47 (21): 8063–8082. doi:10.1021/ie8008764. ISSN 0888-5885.
^Nezbeda, Ivo (2020-09-29). "On Molecular-Based Equations of State: Perturbation Theories, Simple Models, and SAFT Modeling". Frontiers in Physics. 8: 287. Bibcode:2020FrP.....8..287N. doi:10.3389/fphy.2020.00287. ISSN 2296-424X.
^Gubbins, Keith E. (2016-05-25). "Perturbation theories of the thermodynamics of polar and associating liquids: A historical perspective". Fluid Phase Equilibria. Special Issue: SAFT 2015. 416: 3–17. doi:10.1016/j.fluid.2015.12.043. ISSN 0378-3812.
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