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Sodium metaborate information


Sodium metaborate

Sodium metaborate monomer

Sodium metaborate trimer
Names
IUPAC name
Sodium metaborate
Identifiers
CAS Number
  • 7775-19-1 checkY
3D model (JSmol)
  • Interactive image
ChEBI
  • CHEBI:75227
ECHA InfoCard 100.028.992 Edit this at Wikidata
EC Number
  • 231-891-6
PubChem CID
  • 145326
RTECS number
  • ED4640000
UNII
  • Z6Q395A23R checkY
CompTox Dashboard (EPA)
  • DTXSID2034386 Edit this at Wikidata
InChI
  • InChI=1S/BO2.Na/c2-1-3;/q-1;+1
    Key: NVIFVTYDZMXWGX-UHFFFAOYSA-N
SMILES
  • B(=O)[O-].[Na+]
Properties
Chemical formula
NaBO2
Molar mass 65.80 g·mol−1
Appearance Colorless crystals
Odor Odorless
Density 2.464 g/cm3 (anhydrous)[1]
Melting point 966 °C (1,771 °F; 1,239 K)
Boiling point 1,434[2] °C (2,613 °F; 1,707 K)
Solubility in water
16.4 g/(100 mL) (0 °C)
28.2 g/(100 mL) (25 °C)
125.2 g/(100 mL) (100 °C)
Solubility insoluble in ether, ethanol
Structure
Crystal structure
trigonal
Thermochemistry
Heat capacity (C)
65.94 J/(mol·K)
Std molar
entropy (S298)
73.39 J/(mol·K)
Std enthalpy of
formation fH298)
−1059 kJ/mol
Hazards
Lethal dose or concentration (LD, LC):
LD50 (median dose)
2330 mg/kg (rat, oral)
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references

Sodium metaborate is a chemical compound of sodium, boron, and oxygen with formula NaBO2.[3] However, the metaborate ion is trimeric in the anhydrous solid, therefore a more correct formula is Na3B3O6 or (Na+)3[B3O6]3−. The formula can be written also as Na2O·B2O3 to highlight the relation to the main oxides of sodium and boron.[2] The name is also applied to several hydrates whose formulas can be written NaBO2·nH2O for various values of n.

The anhydrous and hydrates are colorless crystalline solids. The anhydrous form is hygroscopic.[4]

  1. ^ Cite error: The named reference fang1938 was invoked but never defined (see the help page).
  2. ^ a b Cite error: The named reference cole1935 was invoked but never defined (see the help page).
  3. ^ Cite error: The named reference Chemister was invoked but never defined (see the help page).
  4. ^ Cite error: The named reference zach1937 was invoked but never defined (see the help page).

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Sodium metaborate

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Sodium metaborate is a chemical compound of sodium, boron, and oxygen with formula NaBO2. However, the metaborate ion is trimeric in the anhydrous solid...

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Metaborate

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(e.g. salts such as sodium metaborate NaBO2 or calcium metaborate Ca(BO2)2, and esters such as methyl metaborate CH3BO2). Metaborate is one of the boron's...

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Sodium borohydride

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Hasan K. Atiyeh and Boyd R. Davis (2007): "Separation of sodium metaborate from sodium borohydride using nanofiltration membranes for hydrogen storage...

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Sodium borate

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system sodium oxide-boric oxide-water. Revised solubility-temperature curves of boric acid, borax, sodium pentaborate, and sodium metaborate". Journal...

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Borate

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such as orthoborate BO3−3, metaborate BO−2, or tetraborate B4O2−7; or any salt of such anions, such as sodium metaborate, Na+[BO2]− and borax (Na+)2[B4O7]2−...

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Trisodium orthoborate

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mixture of sodium metaborate NaBO2 and trisodium borate proper. and "sodium borate" is sometimes used in the generic sense, for a sodium salt with any...

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Sodium chlorate

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approximately 53% sodium chlorate with the balance being a fire depressant such as sodium metaborate or ammonium phosphates. Sodium chlorate is the active...

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Sodium perborate

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sodium hydroxide NaOH to give sodium metaborate NaBO2, which is then reacted with hydrogen peroxide to give hydrated sodium perborate: Na2B4O7 + 2 NaOH → 4...

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Gypsum

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highly soluble form of boron (sodium metaborate) is converted to the less soluble calcium metaborate. Exchangeable sodium percentage is also reduced by...

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Cyclic compound

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other cyclic phosphoric acid derivatives), boron and oxygen (e.g., sodium metaborate Na3(BO2)3, borax), boron and nitrogen (e.g. borazine (BN)3H6).[citation...

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Direct borohydride fuel cell

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after sodium borohydride (NaBH4) has released its hydrogen and has been oxidized, the product is NaBO2 (sodium metaborate). Sodium metaborate might be...

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Sodium tetrahydroxyborate

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solution for evaporative crystallization can be prepared also from sodium metaborate tetrahydrate NaBO2·4H2O. The solid is fairly stable but slowly reacts...

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Photographic processing

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premises in some areas. Borates, such as borax (sodium tetraborate), boric acid and sodium metaborate, are toxic to plants, even at a concentration of...

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Fernico

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lead-alkali glasses. This wire is often coated with a glass-like film of sodium metaborate, (NaBO 2), so the molten glass will "wet" and adhere to it. 25% by...

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Solubility table

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205 257 295 302 Sodium metabisulfite Na2S2O5 45.1 65.3 88.7 96.3 Sodium metaborate NaBO2 16.4 20.8 25.4 31.4 40.4 63.9 84.5 125.2 Sodium molybdate Na2MoO4...

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Bead test

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forming a colourless, transparent glass-like bead (a mixture of sodium metaborate and boric anhydride). The bead is allowed to cool and then wetted...

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Pyrogallol

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ingredients: pyrogallol, Metol, and Kodalk (the trade name of Kodak for sodium metaborate). This formulation resolved the consistency issues, and Hutchings...

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Barium borate

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pigment. Barium borate dihydrate is prepared from the solution of sodium metaborate and barium chloride at 90–95 °C. After cooling to room temperature...

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Metaboric acid

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H2B4O7 + H2O Metaborates are derivatives of BO2−. Like metaboric acid, the metaborates exist with disparate structures. Examples are sodium and potassium...

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Disodium enneaborate

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of sodium, boron, oxygen, and hydrogen, with elemental formula Na2B9H22O20 or Na2B9O9·11H2O. It is the sodium borate with the highest boron/sodium ratio...

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Tetrahydroxyborate

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to a high temperature, tetrahydroxyborate salts decompose to produce metaborate salts and water, or to produce boric acid and a metal hydroxide: n [B(OH)4]−...

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List of additives used for fracking

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7775-19-1 Sodium Metaborate .8H2O 10486-00-7 Sodium perborate tetrahydrate 7775-27-1 Sodium persulfate 9003-04-7 Sodium polyacrylate 7757-82-6 Sodium sulfate...

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Sodalite

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Smith; S. Garcia-Blanco; L. Rivoir (1961). "A new structural type of metaborate anion". Zeitschrift für Kristallographie. 115 (1–6): 460–463. doi:10.1524/zkri...

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Oxyacid

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of sodium hydroxide, water, is 14.0, while that of sodium amide, ammonia, is closer to 40, making sodium hydroxide a much weaker base than sodium amide...

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List of CAS numbers by chemical compound

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carbide 12012–35–0 Cr3O4 chromium(II,III) oxide 12018–34–7 CsBO2 caesium metaborate 92141–86–1 CsBr caesium bromide 7787–69–1 CsBrO3 caesium bromate 13454–75–6...

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Borate oxalate

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benzene. When heated, oxalaotoborates decompose at around 320 °C to yield a metaborate, carbon monoxide, and carbon dioxide. Bessler, Eberhard; Weidlein, Johann...

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List of minerals recognized by the International Mineralogical Association

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[HCO3] Nitrates (subclass 5.N): nitrates [NO3] Borate class (class 6): metaborates [B2O4], trioxoborate [BO3], tetrahydroborate [B(OH)4] Mineral structures...

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Synthesis of carbon nanotubes

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Xirui; Liu, Xinye; Licht, Gad; Licht, Stuart (2020-09-15). "Calcium metaborate induced thin walled carbon nanotube syntheses from CO2 by molten carbonate...

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