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Sodium ethyl xanthate information


Sodium ethyl xanthate
Ball-and-stick model of the component ions of sodium ethyl xanthate
Names
IUPAC name
sodium O-ethylcarbonodithioate
Other names
Sodium ethylxanthogenate
Sodium-O-ethyl dithiocarbonate
SEX
Identifiers
CAS Number
  • 140-90-9 checkY
3D model (JSmol)
  • Interactive image
Abbreviations SEX
ChemSpider
  • 8493 checkY
ECHA InfoCard 100.004.947 Edit this at Wikidata
EC Number
  • 205-440-9
PubChem CID
  • 23690437
UNII
  • 3R5A3652VK checkY
CompTox Dashboard (EPA)
  • DTXSID1044801 Edit this at Wikidata
InChI
  • InChI=1S/C3H6OS2.Na/c1-2-4-3(5)6;/h2H2,1H3,(H,5,6);/q;+1/p-1
    Key: RZFBEFUNINJXRQ-UHFFFAOYSA-M
SMILES
  • CCOC(=S)[S-].[Na+]
Properties
Chemical formula
C3H5NaOS2
Molar mass 144.18 g·mol−1
Appearance Pale yellow powder[1]
Density 1.263 g/cm3[1]
Melting point 182 to 256 °C (360 to 493 °F; 455 to 529 K)[1]
Boiling point decomposes
Solubility in water
450 g/L (10 °C)[1]
Acidity (pKa) 1.6[1]
Basicity (pKb) 12.4[1]
Hazards
GHS labelling:
Pictograms
GHS02: FlammableGHS05: CorrosiveGHS06: ToxicGHS07: Exclamation mark
Signal word
Danger
Hazard statements
H228, H302, H311, H314, H315, H319, H332, H335
Precautionary statements
P210, P240, P241, P260, P261, P264, P270, P271, P280, P301+P312, P301+P330+P331, P302+P352, P303+P361+P353, P304+P312, P304+P340, P305+P351+P338, P310, P312, P321, P322, P330, P332+P313, P337+P313, P361, P362, P363, P370+P378, P403+P233, P405, P501
Autoignition
temperature
250 °C (482 °F; 523 K)[2]
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references

Sodium ethyl xanthate (SEX)[3] is an organosulfur compound with the chemical formula CH3CH2OCS2Na. It is a pale yellow powder, which is usually obtained as the dihydrate. Sodium ethyl xanthate is used in the mining industry as a flotation agent.[4] A closely related potassium ethyl xanthate (KEX) is obtained as the anhydrous salt.

  1. ^ a b c d e f Report 5 (1995) p. 5
  2. ^ Report 5 (1995) p. 6
  3. ^ Caroline Cooper (23 July 2010). Organic Chemist's Desk Reference. CRC Press. pp. 123 (Acronyms and Miscellaneous Terms used in Describing Organic Molecules). ISBN 978-1-4398-1164-1. Retrieved 22 February 2011.
  4. ^ Kathrin-Maria Roy (2005). "Xanthates". Ullmann's Encyclopedia of Industrial Chemistry. Weinheim: Wiley-VCH. doi:10.1002/14356007.a28_423. ISBN 3527306730.

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Sodium ethyl xanthate

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Sodium ethyl xanthate (SEX) is an organosulfur compound with the chemical formula CH3CH2OCS2Na. It is a pale yellow powder, which is usually obtained...

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Xanthate

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xanthate salts include: sodium ethyl xanthate CH3CH2OCS2Na potassium ethyl xanthate, CH3CH2OCS2K potassium isopropyl xanthate, (CH3)2CHOCS2K sodium isobutyl...

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Potassium ethyl xanthate

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Potassium ethyl xanthate (KEX) is an organosulfur compound with the chemical formula CH3CH2OCS2K. It is a pale yellow powder that is used in the mining...

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Froth flotation

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xanthate salts, including potassium amyl xanthate (PAX), potassium isobutyl xanthate (PIBX), potassium ethyl xanthate (KEX), sodium isobutyl xanthate...

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Isopropyl alcohol

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March 2024. Intel application method arcticsilver.com "Sodium Isopropyl Xanthate, SIPX, Xanthate". 3DChem.com. Archived from the original on 4 May 2012...

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List of chemical compounds with unusual names

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flavonol dye derived from buckthorn (rhamnus). SEX An abbreviation of sodium ethyl xanthate, a flotation agent used in the mining industry. Spermine, Spermidine...

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Thioxanthate

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preparation of sodium ethyl thioxanthate:. EtSH + NaOH + CS2 → EtSCS− 2Na+ + H2O Sodium ethyl thioxanthate is similar structurally to sodium ethyl xanthate. Alkylation...

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Ester

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mimic those odors. List of esters Amide Thioamide Carboximidate Carbamate Xanthate Amidine Cyanate Thiocyanate Selenocyanate Tellurocyanate Polyester, plastics...

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Oxime

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Examples are the reaction of ethyl acetoacetate and sodium nitrite in acetic acid, the reaction of methyl ethyl ketone with ethyl nitrite in hydrochloric acid...

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Alkyl nitrite

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first few members of the series are volatile liquids; methyl nitrite and ethyl nitrite are gaseous at room temperature and pressure. The compounds have...

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Alkoxy group

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methoxy (CH3O−). An ethoxy group (CH3CH2O−) is found in the organic compound ethyl phenyl ether (C6H5OCH2CH3, also known as ethoxybenzene). Related to alkoxy...

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Carbamate

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carbamic acid (NH2COOH). The term includes organic compounds (e.g., the ester ethyl carbamate), formally obtained by replacing one or more of the hydrogen atoms...

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Nitro compound

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α-nitro carboxylic acids formed from nitriles and ethyl nitrate. In nucleophilic aliphatic substitution, sodium nitrite (NaNO2) replaces an alkyl halide. In...

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Ether

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are a composite of the two substituents followed by "ether". For example, ethyl methyl ether (CH3OC2H5), diphenylether (C6H5OC6H5). As for other organic...

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Thiol

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of smell. Methanethiol – CH3SH [methyl mercaptan] Ethanethiol – C2H5SH [ethyl mercaptan] 1-Propanethiol – C3H7SH [n-propyl mercaptan] 2-Propanethiol –...

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Thiocarbonate

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dithiocarbonates are the xanthates (O-esters of dithiocarbonates), with the formula ROCS−2. These salts are typically prepared by the reaction of sodium alkoxides with...

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Diethyl dixanthogen disulfide

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J.O. (1990). "FTIR and Flotation Investigation of the Adsorption of Ethyl Xanthate on Activated and Non-Activated Sulfide Minerals". International Journal...

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Organic peroxides

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adjusted by suitable choice of temperature and type of peroxide. Methyl ethyl ketone peroxide, benzoyl peroxide and to a smaller degree acetone peroxide...

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Carboxylic acid

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ethers and alcohols. Aqueous sodium hydroxide and carboxylic acids, even hydrophobic ones, react to yield water-soluble sodium salts. For example, enanthic...

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Ketone

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example methyl ethyl ketone. However, according to the rules of IUPAC nomenclature, the alkyl groups are written alphabetically, for example ethyl methyl ketone...

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Methoxy group

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v t e Functional groups Hydrocarbons (only C and H) Alkyl Methyl Ethyl Propyl Cyclopropyl Butyl Pentyl Methylene Bridge Methine Alkene Vinyl Allyl 1-Propenyl...

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Peroxide

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group element). Metal peroxides, examples being barium peroxide (BaO2), sodium peroxide (Na2O2) and zinc peroxide (ZnO2). Organic peroxides, compounds...

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Sulfonic acid

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as −6.5. Sulfonic acids are known to react with solid sodium chloride (salt) to form the sodium sulfonate and hydrogen chloride. This property implies...

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Benzyl group

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Treatment of alcohol with a strong base such as powdered potassium hydroxide or sodium hydride and benzyl halide (BnCl or BnBr) Monobenzylation of diols can be...

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Acetoxy group

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an aqueous base would. (Same also holds with an ethoxide in ethanol with ethyl esters) Acetyl group Acetylation Nomenclature of Organic Chemistry : IUPAC...

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Methyl group

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Cyanate

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acceptors. It can be described as an ambidentate ligand. Sodium cyanate is isostructural with sodium fulminate, confirming the linear structure of the cyanate...

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Functional group

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