The Shell higher olefin process (SHOP) is a chemical process for the production of linear alpha olefins via ethylene oligomerization and olefin metathesis invented and exploited by Royal Dutch Shell.[1] The olefin products are converted to fatty aldehydes and then to fatty alcohols, which are precursors plasticizers and detergents. The annual global production of olefines through this method is over one million tonnes.[2]
^Industrial Organic Chemistry, Klaus Weissermel, Hans-Jurgen Arpe John Wiley & Sons; 3rd 1997 ISBN 3-527-28838-4
^Keim, W. (2013), Oligomerization of Ethylene to α-Olefins: Discovery and Development of the Shell Higher Olefin Process (SHOP). Angew. Chem. Int. Ed., 52: 12492–12496. doi:10.1002/anie.201305308
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The Shellhigherolefinprocess (SHOP) is a chemical process for the production of linear alpha olefins via ethylene oligomerization and olefin metathesis...
practiced, however. Shellhigherolefinprocess (SHOP) produces (alpha-olefins) for conversion to detergents. The process recycles certain olefin fractions using...
effected by the alphabutol process, giving 1-butene, and the Shellhigherolefinprocess which gives a range of alpha-olefins. The former is based on titanium-based...
Long chain oxo-alcohols are often prepared using alpha-olefins from the Shellhigherolefinprocess, to give secondary alcohols such as isodecyl alcohol...
may be produced, for example in the Shellhigherolefinprocess, where α-olefins are extended to make longer α-olefins by adding ethylene repeatedly. Some...
processes including carbonylations, hydrocyanation, and the Shellhigherolefinprocess. A popular reagent is Ni(CH3)2(tetramethylethylenediamine). Many...
versions. Related technologies include the ShellHigherOlefinProcess which produces detergent precursors. the olefin can be coordinated to the metal before...
catalysts. This process is employed in the Shellhigherolefinprocess to convert alpha-olefins to internal olefins, which are subjected to olefin metathesis...
SHOP) .shop, a top-level domain Shellhigherolefinprocess, or SHOP, a chemical process for the production of α-olefins Charity shop Give-away shop Shop...
carbon monoxide, and H2. Hydroformylation is coupled to the Shellhigherolefinprocess to give precursors to detergents. Phosgene, useful for preparing...
C8H17CH2CH2CHO C8H17CH2CH2CHO + H2 → C8H17CH2CH2CH2OH In the Shellhigherolefinprocess, the chain-length distribution in the initial mixture of alkene...
classes are olefins (including ethylene and propylene) and aromatics (including benzene, toluene and xylene isomers). Oil refineries produce olefins and aromatics...
technologies include the ShellHigherOlefinProcess which produces detergent precursors. Factors affecting the rate of olefin insertions include the formation...
160 to 180 °C. The Shellprocess uses cobalt complexes modified with phosphine ligands for the hydroformylation of C7–C14 olefins. The resulting aldehydes...
ethenolysis, higher molecular weight internal alkenes can be converted to more valuable terminal alkenes. The Shellhigherolefinprocess (SHOP process) uses...
measurable quality. Poly-alpha-olefin (poly-α-olefin, PAO) is a non-polar polymer made by polymerizing an alpha-olefin. They are designated at API Group...
one of the key figures in the development of the SHOP – process (Shellhigherolefinprocess). SHOP-olefines have a broad range of applications in industrial...
Eichwald, "Process and product relating to olefin derivatives", published 1936-09-22, assigned to Shell Development Co. US 2230005, F.R. Moser, "Process for...
Technology ExxonMobil Research and Engineering (EMRE) Shell Global Solutions Axens / Stone & Webster Process Technology — currently owned by Technip UOP LLC...
concentration of olefins. In 1940, there were only 14 Houdry units in operation in the U.S.; by 1943, this had increased to 77, either of the Houdry process or of...
and co-catalysts. Methylaluminoxane is a co-catalyst for Ziegler–Natta olefin polymerization to produce vinyl polymers such as polyethene. Aqueous aluminium...
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