Rieche formylation is a type of formylation reaction. The substrates are electron rich aromatic compounds, such as mesitylene[1] or phenols,[2] with dichloromethyl methyl ether acting as the formyl source. The catalyst is titanium tetrachloride and the workup is acidic. The reaction is named after Alfred Rieche who discovered it in 1960.[3]
Riecheformylation is a type of formylation reaction. The substrates are electron rich aromatic compounds, such as mesitylene or phenols, with dichloromethyl...
Riecheformylation A particularly important formylation process is hydroformylation, which converts alkenes to the homologated aldehyde. Formylation reactions...
Alfred Rieche (28 April 1902 – 6 November 2001) was a German chemist. "Alfred RIECHE * 28.4.1902 † 6.11.2001". Archived from the original on 2009-10-09...
chlorodimethyl ether. The compound is used in the formylation of aromatic compounds (Riecheformylation) and as a chlorination agent in the formation of...
synthesis of 3-thiazolines. Alfred Rieche - chemist who discovered the Riecheformylation, a type of formylation reaction. Fritz Karl Preikschat - electrical...
synthesis of 3-thiazolines. Alfred Rieche - chemist who discovered the Riecheformylation, a type of formylation reaction. Fritz Karl Preikschat - electrical...
benzocyclobutene 2 and further pyrolyzed to the cyclooctane dimer 3. Riecheformylation afforded 4 (after separation from other regioisomers), aldehyde reduction...
reagents are useful in the preparation of derivatives of benzaldehyde by formylation and for the conversion of C−OH groups into C−Cl groups. It is especially...