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Dichloromethyl methyl ether information


Dichloromethyl methyl ether
Names
Preferred IUPAC name
Dichloro(methoxy)methane
Identifiers
CAS Number
  • 4885-02-3
3D model (JSmol)
  • Interactive image
ChemSpider
  • 19757
ECHA InfoCard 100.023.180 Edit this at Wikidata
PubChem CID
  • 21004
CompTox Dashboard (EPA)
  • DTXSID2063636 Edit this at Wikidata
InChI
  • InChI=1S/C2H4Cl2O/c1-5-2(3)4/h2H,1H3
SMILES
  • ClC(Cl)OC
Properties
Chemical formula
C2H4Cl2O
Molar mass 114.95 g·mol−1
Boiling point 85°C
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references

Dichloromethyl methyl ether (HCl2COCH3) is an organic compound that belongs to the class of ethers with a dichloromethyl group and a methyl group. It can be synthesized from methyl formate and a mixture of phosphorus pentachloride and phosphorus oxychloride[1] or by chlorination of chlorodimethyl ether.

The compound is used in the formylation of aromatic compounds (Rieche formylation) and as a chlorination agent in the formation of acid chlorides.[2]

  1. ^ Organic Syntheses, Coll. Vol. 5, p.365 (1973); Vol. 47, p.51 (1967). link
  2. ^ Organic Syntheses, Coll. Vol. 7, p.467 (1990); Vol. 61, p.1 (1983). Link

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Dichloromethyl methyl ether

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Dichloromethyl methyl ether (HCl2COCH3) is an organic compound that belongs to the class of ethers with a dichloromethyl group and a methyl group. It...

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Rieche formylation

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rich aromatic compounds, such as mesitylene or phenols, with dichloromethyl methyl ether acting as the formyl source. The catalyst is titanium tetrachloride...

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Chloroalkyl ether

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to a chloromethyl group via an alkane chain. Chloromethyl methyl ether (CMME) is an ether with the formula CH3OCH2Cl. It is used as an alkylating agent...

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Phosphorus pentachloride

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ISBN 0471936235. Gross, H.; Rieche, A.; Höft, E.; Beyer, E. (1973). "Dichloromethyl methyl ether". Organic Syntheses; Collected Volumes, vol. 5, p. 365. Spaggiari...

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C2H4Cl2O

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exact mass: 113.9639 u) may refer to: Bis(chloromethyl) ether Dichloromethyl methyl ether This set index page lists chemical structure articles associated...

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IARC group 2B

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hydrochloride Phenyl glycidyl ether ortho-Phenylenediamine ortho-Phenylenediamine dihydrochloride Phenytoin PhIP (2-amino-1-methyl-6-phenylimidazo(4,5-b)pyridine)...

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Formylation

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Lewis acid catalysts: Chloroform in the Reimer-Tiemann reaction Dichloromethyl methyl ether in Rieche formylation A particularly important formylation process...

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Chloroform

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P-450 enzymes, by oxidation to chloromethanol and by reduction to the dichloromethyl free radical. Other metabolites of chloroform include hydrochloric acid...

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California Proposition 65 list of chemicals

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1-(2-Chloroethyl)-3-(4-methylcyclohexyl)-1-nitrosourea (Methyl-CCNU) 13909-09-6 Chloroform 67-66-3 Chloromethyl methyl ether 107-30-2 3-Chloro-2-methylpropene 563-47-3...

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