Adsorption is the adhesion of ions or molecules onto the surface of another phase.[1] Adsorption may occur via physisorption and chemisorption. Ions and molecules can adsorb to many types of surfaces including polymer surfaces. A polymer is a large molecule composed of repeating subunits bound together by covalent bonds. In dilute solution, polymers form globule structures. When a polymer adsorbs to a surface that it interacts favorably with, the globule is essentially squashed, and the polymer has a pancake structure.[2]
^H.J. Butt; K. Graf & M. Kappl (2006). "Adsorption". Physics and Chemistry of Interfaces (2 ed.). Federal Republic of Germany: Wiley-VCH. pp. 187–217. ISBN 978-3-527-40629-6.
^Carroll, Gregory T.; Jongejan, Mahthild G. M.; Pijper, Dirk; Feringa, Ben L. (2010). "Spontaneous generation and patterning of chiral polymeric surface toroids". Chemical Science. 1 (4): 469. doi:10.1039/c0sc00159g. ISSN 2041-6520. S2CID 96957407.
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thermodynamics of adsorption can be used to understand the driving forces for adsorption. To measure the thermodynamics of polymer surfaces, contact angles...
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surface area available for adsorption or chemical reactions that can be thought of as a microscopic "sponge" structure. (Adsorption, not to be confused with...
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repulsive forces. This theory can be applied to the adsorption of small molecules like mucoadhesive polymers, on surfaces, like mucus layers. Particles in general...
(1996). "Kinetics and jamming coverage in a random sequential adsorption of polymer chains". Phys. Rev. Lett. 77 (9): 1773–1776. arXiv:cond-mat/9605038...