Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Chemical compound
Pinacolone (3,3-dimethyl-2-butanone) is an important ketone in organic chemistry. It is a colorless liquid and has a slight peppermint- or camphor- odor. It is a precursor to triazolylpinacolone in the synthesis of the fungicide triadimefon and in synthesis of the herbicide metribuzin. The molecule is an unsymmetrical ketone. The α-methyl group can participate in condensation reactions. The carbonyl group can undergo the usual reactions (hydrogenation, reductive amination, etc.). It is a Schedule 3 compound under the Chemical Weapons Convention 1993, due to being related to pinacolyl alcohol, which is used in the production of soman.[2] It is also a controlled export in Australia Group member states.[3]
^"Pinacolone | C6H12O | ChemSpider".
^Handbook of chemical and biological warfare agents (2nd ed.). CRC Press. 24 August 2007. ISBN 9780849314346.
^"Export Control List: Chemical Weapons Precursors". Australia Group. australiagroup.net. Retrieved 7 April 2017.
Pinacolone (3,3-dimethyl-2-butanone) is an important ketone in organic chemistry. It is a colorless liquid and has a slight peppermint- or camphor- odor...
The pinacol–pinacolone rearrangement is a method for converting a 1,2-diol to a carbonyl compound in organic chemistry. The 1,2-rearrangement takes place...
coupling reaction from acetone: As a vicinal-diol, it can rearrange to pinacolone by the pinacol rearrangement, e.g. by heating with sulfuric acid: Pinacol...
ampicillin and amoxycillin. It was originally prepared by the oxidation of pinacolone with chromic acid and by the hydrolysis of tert-butyl cyanide. Convenient...
cis-3-Hexen-1-ol Methyl isobutyl ketone 3-Methyl-2-pentanone Oxepane Pinacolone This set index page lists chemical structure articles associated with...
3-dimethylbutane-2,3-diol and methyl tert-butyl ketone, better known as pinacolone. Pinacolone itself is then used in synthesis for number of pesticides. Additionally...
Seebach, Dieter (1988). "Structure and Reactivity of Lithium Enolates. From Pinacolone to SelectiveC-Alkylations of Peptides. Difficulties and Opportunities...
Seebach, D (1988). "Structure and Reactivity of Lithium Enolates. From Pinacolone to Selective C-Alkylations of Peptides. Difficulties and Opportunities...
filed by an ICI group working at Jealott's Hill. 4-Chlorobenzaldehyde and pinacolone are combined in an aldol condensation to form a chalcone which is hydrogenated...
from acetone, followed by the rearrangement to 3,3-dimethylbutanone (pinacolone), which was then oxidised with dichromate to trimethylacetic acid. Fittig's...
[verification needed] Some spiro compounds can be synthesized using the Pinacol-pinacolone rearrangement;: 985 for example, spiro[4.5]decane (final compound in...
with Benzophenone and of Methylmagnesium Bromide-Magnesium Bromide with Pinacolone". J. Org. Chem. 27 (2): 596–598. doi:10.1021/jo01049a060. Richard A. Andersen...
guest molecules in clathrates of many larger organic molecules, such as pinacolone and tetrahydrofuran. In such cases the guest-host hydrogen bonds result...
enolate. This effect is particularly evident with the lithium enolate of pinacolone, which gives a 2:1 mixture favoring C-attack. More substituted lithium...
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