Palladacycle, as a class of metallacycles, refers to complexes containing at least one carbon-palladium bond. Palladacycles are invoked as intermediates in catalytic or palladium mediated reactions. They have been investigated as pre-catalysts for homogeneous catalysis and synthesis.
phosphine-derived palladacycle. Other types of palladacycles such as phosphite palladacycle, imine palladacycle, oxime palladacycle, CS-/CO-palladacycles are also...
Palladium-Catalyzed Synthesis of Methyl Aryl Ethers Enabled by the Use of a Palladacycle Precatalyst". Organic Letters. 15 (15): 3998–4001. doi:10.1021/ol401796v...
General Conditions for Negishi Cross-Coupling Enabled by the Use of Palladacycle Precatalysts". Angew. Chem. Int. Ed. 52 (2): 615–619. doi:10.1002/anie...
Reisinger, C.-P.; Riermeier, T. H.; Öfele, K.; Beller, M. (1997). "Palladacycles: Efficient New Catalysts for the Heck Vinylation of Aryl Halides". Chemistry...
anti-Markovnikov carbon to generate the more thermodynamically stable palladacycle. Anti-Markovnikov selectivity is also observed in styrenyl substrates...
Aminoboration of Alkenyl Carbonyl Compounds via Five- and Six-Membered Palladacycles". Journal of the American Chemical Society. 140 (9): 3223–3227. doi:10...
with two Pd migrations) equilibria are postulated between different palladacycles: and in certain intramolecular couplings synthetic value was demonstrated...
general conditions for negishi cross-coupling enabled by the use of palladacycle precatalysts". Angewandte Chemie. 52 (2): 615–9. doi:10.1002/anie.201207750...
and trans-bicyclic sulfamides. It has also been used to synthesize palladacycle precatalysts for Negishi coupling of secondary alkylzinc reagents with...
Pullarkat, S. A.; Teong, S.; Chew, R. J.; Li, Y.; Leung, P. H. (2012). "Palladacycle-Catalyzed Asymmetric Intermolecular Construction of Chiral Tertiary P-Heterocycles...
C−H alkylation and C−C bond cleavage enabled by an in situ generated palladacycle". Nature Chemistry. 9 (4): 361–368. doi:10.1038/nchem.2631. PMID 28338687...
Reisinger, C. P.; Riermeier, T. H.; Öfele, K.; Beller, M. (1997). "Palladacycles: Efficient New Catalysts for the Heck Vinylation of Aryl Halides". Chem...
M. (2017-11-08). "Tridentate Directing Groups Stabilize 6-Membered Palladacycles in Catalytic Alkene Hydrofunctionalization". Journal of the American...
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