Organomanganese chemistry is the chemistry of organometallic compounds containing a carbon to manganese chemical bond. In a 2009 review, Cahiez et al. argued that as manganese is cheap and benign (only iron performs better in these aspects), organomanganese compounds have potential as chemical reagents, although currently they are not widely used as such despite extensive research.[1]
Organomanganesechemistry is the chemistry of organometallic compounds containing a carbon to manganese chemical bond. In a 2009 review, Cahiez et al....
Morris, Robert J.; Girolami, Gregory S. (1991). "High-valent organomanganesechemistry. 1. Synthesis and characterization of manganese(III) and -(IV)...
are believed not the active species. Instead, they transmetalate to organomanganese compounds, which then decompose to tert-butyl radicals, which dimerize...
oxyhalides. The oxychlorides are most common, and include ReOCl4, ReOCl3. Organomanganese compounds were first reported in 1937 by Gilman and Bailee who described...
Methylcyclopentadienyl manganese tricarbonyl (MMT or MCMT) is an organomanganese compound with the formula (C5H4CH3)Mn(CO)3. Initially marketed as a supplement...
hydride, or alkylated with organic halides to give a large swath of organomanganese(I) complexes. Homolytic cleavage, usually via light, but sometimes...
Synthesis and Structure- Property Relationships in η6-Arene) Cr(CO)3 Chemistry: From Guided Experiments to Discovery Research. J. Chem. Educ. 75. 1998...
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