Study of chemical compounds containing lanthanide-carbon bonds
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Organolanthanide chemistry is the field of chemistry that studies organolanthanides, compounds with a lanthanide-to-carbon bond. Organolanthanide compounds are different from their organotransition metal analogues in the following ways:
They are far more air- and water-sensitive and are often pyrophoric.
Chemistry in the 0 oxidation state is far more limited. In fact, their electropositive nature makes their organometallic compounds more likely to be ionic.
They form no stable carbonyls at room temperature; organolanthanide carbonyl compounds have been observed only in argon matrices, and decompose when heated to 40 K.
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Organolanthanidechemistry is the field of chemistry that studies organolanthanides, compounds with a lanthanide-to-carbon bond. Organolanthanide compounds...
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between carbon and cerium. These compounds comprise a subset of the organolanthanides. Most organocerium compounds feature Ce(III) but some Ce(IV) derivatives...
on the use of molten salts in catalysis and initiated work on organolanthanidechemistry. He conducted early studies related to nitrogen fixation. He was...
hydroamination has been well studied. Particularly well studied is the organolanthanide catalyzed intramolecular hydroamination of alkenes. First, the catalyst...
and a higher covalent character to the carbon-actinide bond than in organolanthanide compounds. Tetravalent thorium, uranium and neptunium easily form MCp4...
1975). "Organolanthanides and organoactinides. XV. Synthesis and properties of new .sigma.-bonded organolanthanide complexes". Inorganic Chemistry. 14 (11):...
an Order of Australia (AO) and he was also the author of A Handbook of Chemistry, initially published by the Shakespeare Head Press and later by his own...
Organometallic chemistry in CRD has further included R. Thomas Baker's heterobinuclear complexes, Patricia L. Watson's organolanthanides, William A. Nugent's...
Fragalà, I. L.; Marks, T. J. (2005). "Energetics and Mechanism of Organolanthanide-Mediated Phosphinoalkene Hydrophosphination/Cyclization. A Density...
from the University of California, Berkeley for his research on organolanthanidechemistry with Professor Richard A. Andersen. Afterwards, he conducted post-doctoral...
complex of praseodymium(IV) has recently been reported. Like the other organolanthanide compounds, properties of organopraseodymium compounds include: Organopraseodymium...
Hubert; Gade, Lutz H. (1 January 2007). "High tacticity control in organolanthanide polymerization catalysis: formation of isotactic poly(α-alkenes) with...
the chemistry of organolanthanides. Beletskaya was born in Leningrad (St. Petersburg, Russia) in 1933. She graduated from the Department of Chemistry of...
electronics. Evans, William J. The Expansion of Divalent Organolanthanide Reduction Chemistry Via New Molecular Divalent Complexes and Sterically Induced...
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