Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Chemical compound
Norbornadiene is an organic compound and a bicyclic hydrocarbon. Norbornadiene is of interest as a metal-binding ligand, whose complexes are useful for homogeneous catalysis. It has been intensively studied owing to its high reactivity and distinctive structural property of being a diene that cannot isomerize (isomers would be anti-Bredt alkenes). Norbornadiene is also a useful dienophile in Diels-Alder reactions.
Norbornadiene is an organic compound and a bicyclic hydrocarbon. Norbornadiene is of interest as a metal-binding ligand, whose complexes are useful for...
of importance as a reagent in Diels-Alder reactions. It reacts with norbornadiene in a sequence of one DA reaction and two retro-DA reactions to cyclopentadiene...
presence of a catalyst, norbornadiene converts to quadricyclane via ~300nm UV radiation . When converted back to norbornadiene, quadryicyclane’s ring strain...
Diels-Alder reaction which is used to form aldrin from a mixture of norbornadiene and hexachlorocyclopentadiene. Originally developed in the 1940s as...
cycloheptene, cyclooctene, and so on. Bicyclic alkenes include norbornene and norbornadiene. Two more examples are shown below, methylenecyclohexane on the left...
(molar mass: 92.14 g/mol) may refer to: Cycloheptatriene Isotoluenes Norbornadiene Quadricyclane Toluene, or toluol This set index page lists chemical...
is higher for freshly distilled norbornadiene, but commercial reagents will suffice. The conversion of norbornadiene into quadricyclane is achieved with...
the metal centre: The compound Ru(COD)(COT) is capable of dimerizing norbornadiene: Multinuclear organo-ruthenium complexes have been investigated for...
labile adducts, including labile but complexes with some noble gases. Norbornadiene was dimerized photochemically in the presence of Cr(CO)6, similarly...
groups from the parent molecule bornane. 2-Norbornyl cation Norbornene Norbornadiene Bornane endo-Norborneol exo-Norborneol Norcamphor, the ketone derivative...
dipolar reaction both become a [4+2]cycloaddition. The reaction between norbornadiene and an activated alkyne is a [2+2+2]cycloaddition. The Diels-Alder reaction...
adducts with many zero-valent metals. Butadiene, cyclooctadiene, and norbornadiene are well-studied chelating agents. Trienes and even some tetraenes can...
The norbornadiene-quadricyclane couple and its derivatives have been extensively investigated for solar energy storage processes. Norbornadiene is converted...
norbornenes can be prepared similarly. Related bicyclic compounds are norbornadiene, which has the same carbon skeleton but with two double bonds, and norbornane...
to form pyridine rings. An alternative to using an alkyne is to use norbornadiene which can be thought of as a masked alkyne. In 2007, a method for synthesizing...
(notice that each double bond is two carbons away from the other). E: Norbornadiene, a strained bicyclic and unconjugated diene. F: Dicyclopentadiene....
into its original isomer). A promising candidate for such a MOST is Norbornadiene (NBD). This is because there is a high energy difference between the...
replaced by two olefins. Many dienes undergo this reaction, notably norbornadiene and 1,3-butadiene. One of the more historically significant derivatives...
carbons of 1,4-cyclohexadiene. OND is related to all-carbon bicycle norbornadiene. While unsubstituted OND is known, the most useful OND derivatives are...
have been proposed as energy storage solutions. The organic compound norbornadiene converts to quadricyclane upon exposure to light, storing solar energy...
"Bridged Ring Compounds. X.1,2 The Reaction of Benzenesulfonyl Azide with Norbornadiene, Dicyclopentadiene, and Bicyclo[2.2.2]-2-octene". The Journal of Organic...
enantiomeric excess. This methodology was expanded to diene substrates such as norbornadiene. These ring strained dienes allowed for sequential, stereoselective...
Aldrin is synthesized by combining hexachlorocyclopentadiene with norbornadiene in a Diels-Alder reaction to give the adduct. In 1967, the composition...
followed in 1993 With a Schrock catalyst modified with a BINOL ligand in a norbornadiene ROMP leading to highly stereoregular cis, isotactic polymer. Alkane...
non-polar. Another azide regular is tosyl azide here in reaction with norbornadiene in a nitrogen insertion reaction: Some azides are valuable as bioorthogonal...
candidate screen based on reactivity. To prevent light-induced reversion to norbornadiene, diethyldithiocarbamate is added to chelate the nickel in the product...
"Ring Strain Energies: Substituted Rings, Norbornanes, Norbornenes and Norbornadienes". Tetrahedron. 60: 8103– 8112. Wiberg, K. B. (1968). "Small Ring Bicyclo[n...
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