A nitroalkene, or nitro olefin, is a functional group combining the functionality of its constituent parts, an alkene and nitro group, while displaying its own chemical properties through alkene activation, making the functional group useful in specialty reactions such as the Michael reaction or Diels-Alder additions.[1]
^Furniss, Brian; Hannaford, Antony; Smith, Peter & Tatchell, Austin (1996). Vogel's Textbook of Practical Organic Chemistry 5th Ed. London: Longman Science & Technical. pp. 635, 768, 1035–1036, & 1121. ISBN 9780582462366.
A nitroalkene, or nitro olefin, is a functional group combining the functionality of its constituent parts, an alkene and nitro group, while displaying...
Oxidation of oximes or primary amines. Reduction of β-nitro alcohols or nitroalkenes. By decarboxylation of α-nitro carboxylic acids formed from nitriles...
reactions with organobromides or organoiodides forming nitro compounds. Nitroalkene synthesis with nitryl iodide generated in-situ from silver nitrite and...
liquid organic compound with the formula C2H3NO2. It is the simplest nitroalkene, which are unsaturated carbon chains with at least one double bond and...
with nitroalkanes is a classic general method for the preparation of nitroalkenes, which are very valuable synthetic intermediates. Beiträge zur Kenntnis...
nitro functional groups, -NO2 Nitro ligand in coordination chemistry Nitroalkene, a functional group combining the functionality of an alkene and nitro...
Phthalic anhydride is used to dehydrate short-chain nitro-alcohols to yield nitroalkenes, compounds with a high tendency to polymerize. The most probable human...
needed] By the Barton–Zard synthesis, an isocyanoacetate reacts with a nitroalkene in a 1,4-addition, followed by 5-endo-dig cyclization, elimination of...
Catalysts for the Enantioselective Michael Addition of Cyclic Ketones to Nitroalkenes". Journal of the American Chemical Society. 128 (30): 9624–9625. doi:10...
precursor and Michael acceptor, such as an aliphatic aldehyde with a nitroalkene. In addition, these substrates tend to be rather activated, as the intermolecular...
Cathodic reduction of a nitroalkene can give the oxime in good yield. At higher negative reduction potentials, the nitroalkene can be reduced further,...
silyl ether (4) as an organocatalyst, along with alkoxyaldehyde (2) and nitroalkene (3) to perform an asymmetric Michael reaction, affording an enantioselective...
cascade was reported by Raabe et al. in 2006. Linear aldehydes (20), nitroalkenes (21) and α,β-unsaturated aldehydes (22) could be condensed together organocatalytically...
intermediates. These conversions include subsequent dehydration to yield nitroalkenes, oxidation of the secondary alcohol to yield α-nitro ketones, or reduction...
selenium intermediate 5. Hydrogen peroxide oxidation of 5 yields the nitroalkene 6 as a mixture of syn and anti isomers. A [4+2]cycloaddition with n-butylenol...
motifs by asymmetric addition of 2-trityloxymethylaryllithiums to nitroalkenes: the asymmetric synthesis of a dopamine D1 full agonist, A-86929". Journal...
media. H-bond accepting substrates include carbonyl compounds, imines, nitroalkenes. The Diels-Alder reaction is one process that can benefit from (thio)urea...
more precisely (E)-1-nitropentadec-1-ene, is a highly toxic unsaturated nitroalkene, the only aliphatic nitro compound known to be synthesized by insects...
cyclopentadiene is described in a number of early papers. The reduction of the nitroalkene may be carried out sequentially. The alkene's double bond is typically...
IMA). Competent Michael acceptors include conjugated enones, enals or nitroalkene derivatives and examples of other acceptors are sparse. Despite IMA reactions...
Catalytic Enantioselective Conjugate Addition of 1,3-Dicarbonyl Compounds to Nitroalkenes for the Synthesis of Endothelin-A Antagonist ABT-546. Scope, Mechanism...
ynolates, novel isocyanates, iron vinylidines, heteroatom functionalized nitroalkenes, and ring closing alkene and enyne metathesis reactions. He has completed...
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