Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references
Chemical compound
Methyl propiolate is an organic compound with the formula HC2CO2CH3. It is the methyl ester of propiolic acid, the simplest acetylenic carboxylic acid. It is a colorless liquid that is miscible with organic solvents. The compound is a reagent and building block for the synthesis of other organic compounds, reactions that exploit the electrophilicity of the alkyne group.[1]
^Hirst, Gavin C. (2001). "Methyl Propiolate". Encyclopedia of Reagents for Organic Synthesis. Encyclopedia of Reagents for Organic Synthesis. doi:10.1002/047084289X.rm237. ISBN 0471936235.
Methylpropiolate is an organic compound with the formula HC2CO2CH3. It is the methyl ester of propiolic acid, the simplest acetylenic carboxylic acid...
cuprous chloride. Propiolates are esters or salts of propiolic acid. Common examples include methylpropiolate and ethyl propiolate. Propargyl Propargyl...
point 187 °C (369 °F; 460 K) Related compounds Related compounds Methylpropiolate, Hexafluoro-2-butyne, Acetylene Except where otherwise noted, data...
similar cycloaddition reaction between Dostál's bismuthinidene and methylpropiolate yields an iminonaphthalene only as an intermediate, as the bridgehead...
carboxylic acid Diketene Dioxins 1,2-Dioxin 1,4-Dioxin 2-Furanone Methylpropiolate Tetrolic acid This set index page lists chemical structure articles...
employing as component parts ammonium acetate, two equivalents of methylpropiolate, and one of 3-nitrobenzaldehyde. Oxidation of the resulting dihydropyridine...
1), the alkyne proton of ethyl propiolate is deprotonated by n-butyllithium at -78 °C to form lithium ethyl propiolate to which cyclopentanone is added...
the Favorskii reaction. Illustrative is the sequence shown below, ethyl propiolate is deprotonated by n-butyllithium to give the corresponding lithium acetylide...
reaction can be generated through the Flash Vacuum Pyrolysis of phenyl propiolate. In organometallic chemistry, azulene serves as a ligand for low-valent...