Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Chemical compound
Lithium amide or lithium azanide is an inorganic compound with the chemical formula LiNH2. It is a white solid with a tetragonal crystal structure.[1] Lithium amide can be made by treating lithium metal with liquid ammonia:[2]
2 Li + 2 NH3 → 2 LiNH2 + H2
^David, William I. F.; Jones, Martin O.; Gregory, Duncan H.; Jewell, Catherine M.; Johnson, Simon R.; Walton, Allan; Edwards, Peter P. (2007-02-01). "A Mechanism for Non-stoichiometry in the Lithium Amide/Lithium Imide Hydrogen Storage Reaction". Journal of the American Chemical Society. 129 (6): 1594–1601. doi:10.1021/ja066016s. ISSN 0002-7863. PMID 17243680.
^P. W. Schenk (1963). "Lithium amide". In G. Brauer (ed.). Handbook of Preparative Inorganic Chemistry, 2nd Ed. Vol. 1. NY, NY: Academic Press. p. 454.
Lithiumamide or lithium azanide is an inorganic compound with the chemical formula LiNH2. It is a white solid with a tetragonal crystal structure. Lithium...
as a nucleophile under certain conditions. LithiumamideLithium bis(trimethylsilyl)amide (LiHMDS) Lithium tetramethylpiperidide (LiTMP) Evans pKa Table...
referred to as alkali metal amides. Examples include lithiumamide, sodium amide, and potassium amide. These salt-like solids are produced by treating liquid...
In organic chemistry, an amide, also known as an organic amide or a carboxamide, is a compound with the general formula R−C(=O)−NR′R″, where R, R', and...
the related reagents sodium hydride, sodium bis(trimethylsilyl)amide (NaHMDS), and lithium diisopropylamide (LDA). Rearrangement with orthodeprotonation...
Lithium hydroxide is an inorganic compound with the formula LiOH. It can exist as anhydrous or hydrated, and both forms are white hygroscopic solids....
will react to form lithiumamide. Li3N + 2 H2 → 2LiH + 2LiNH2 At higher temperatures it will react further to form ammonia and lithium hydride. LiNH2 +...
Like many lithium reagents it has a tendency to aggregate, forming a tetramer in the solid state. Lithium diisopropylamide Lithiumamideamide primer H...
the NH−2 ion). For example, lithium dissolves in liquid ammonia to give a blue solution (solvated electron) of lithiumamide: 2 Li + 2 NH3 → 2 LiNH2 + H2...
Lithium imide is an inorganic compound with the chemical formula Li2NH. This white solid can be formed by a reaction between lithiumamide and lithium...
B family of medications, specifically the vitamin B3 complex. It is an amide of nicotinic acid. Foods that contain niacinamide include yeast, meat, milk...
Potassium amide is an inorganic compound with the chemical formula KNH2. Like other alkali metal amides, it is a white solid that hydrolyzes readily....
elements. For the latter, lithium salts are common e.g. lithium fluoride, lithium hydroxide, lithiumamide, and methyllithium, but lithium boryllides are extraordinarily...
Amide reduction is a reaction in organic synthesis where an amide is reduced to either an amine or an aldehyde functional group. Catalytic hydrogenation...
Lithium aluminium hydride, commonly abbreviated to LAH, is an inorganic compound with the chemical formula Li[AlH4] or LiAlH4. It is a white solid, discovered...
cyclohexanyllithium. Common lithium amides, e.g. lithium bis(trimethylsilyl)amide and lithium diisopropylamide, are also subject to aggregation. Lithium amides adopt...
Vincent Rodeschini, Nigel S. Simpkins, and Fengzhi Zhang (2007). "Chiral LithiumAmide Base Desymmetrization of a Ring Fused Imide: Formation of (3aS,7aS)-2[2-(3...
significant subcategory of metal amide compounds. These compounds tend to be discrete and soluble in organic solvents. Lithium amides are the most important...
solvents are more common. Lithiumamide, LiHMDS, or organolithium reagents, such as butyllithium, are frequently used to form lithium acetylides: H − C ≡ C...
LiOH is present in the n-butyllithium used to make the lithiumamide. Titration of lithiumamide can be used to determine the amount of hydroxide in solution...
The alkali metals consist of the chemical elements lithium (Li), sodium (Na), potassium (K), rubidium (Rb), caesium (Cs), and francium (Fr). Together...
the synthesis of aldehydes by reduction of the amide with an excess of lithium aluminum hydride (see amide reduction). The major advantage of this method...
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