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Hydrotalcite information


Hydrotalcite
Hydrotalcite with serpentine, Snarum, Modum, Buskerud, Norway. Size: 8.4 × 5.2 × 4.1 cm
General
CategoryCarbonate mineral
Formula
(repeating unit)
Mg6Al2CO3(OH)16·4H2O
IMA symbolHtc[1]
Strunz classification5.DA.50
Crystal system3R polytype: Trigonal
2H polytype: Hexagonal
Crystal class3R polytype: Hexagonal scalenohedral (3m)
H-M symbol: (3 2/m)
2H polytype: Dihexagonal dipyramidal (6/mmm)
Space groupR3m
Unit cella = 3.065 Å,
c = 23.07 Å; Z = 3
Identification
ColorWhite with possible brownish tint
Crystal habitSubhedral platey crystals, lamellar-fibrous, rarely euhedral prismatic; commonly foliated, massive
Cleavage{0001}, perfect
TenacityFlexible, not elastic
Mohs scale hardness2
LusterSatiny to greasy or waxy
StreakWhite
DiaphaneityTransparent
Specific gravity2.03–2.09
Optical propertiesUniaxial (−)
Refractive indexnω = 1.511 – 1.531 nε = 1.495 – 1.529
Birefringenceδ = 0.016
Other characteristicsGreasy feel
References[2][3][4][5]

Hydrotalcite, or formerly also völknerite,[6] is a layered double hydroxide (LDH) of general formula Mg
6
Al
2
CO
3
(OH)
16
·4H
2
O
, whose name is derived from its resemblance with talc and its high water content. Multiple structures containing loosely bound carbonate ions exist. The easily exchanged carbonates allow for applications of the mineral in wastewater treatment and nuclear fuel reprocessing.

  1. ^ Warr, L.N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine. 85 (3): 291–320. Bibcode:2021MinM...85..291W. doi:10.1180/mgm.2021.43. S2CID 235729616.
  2. ^ Mindat.org
  3. ^ Handbook of Mineralogy
  4. ^ Webmineral data
  5. ^ "IMA Nomenclature Report" (PDF). Archived from the original (PDF) on 2013-05-24. Retrieved 2012-11-25.
  6. ^ Rammelsberg, C. (1856-05-01). "On völknerite or hydrotalkite, and the so-called steatite of Snarum". The London, Edinburgh, and Dublin Philosophical Magazine and Journal of Science. 11 (73): 405–407. doi:10.1080/14786445608642090. ISSN 1941-5982.

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constitutes the main basis of layered double hydroxide (LDH). LDH minerals as hydrotalcite are powerful anion sorbents but are relatively rare in nature. Brucite...

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rust; ordering, deprotonation and/or cation substitution; structure of hydrotalcite-like compounds and mythic ferrosic hydroxide Fe(OH)2+x. Solid State Sciences...

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Hydrotalcite group mineral...

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