Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Chemical compound
Hexamethylphosphoramide, often abbreviated HMPA, is a phosphoramide (an amide of phosphoric acid) with the formula [(CH3)2N]3PO. This colorless liquid is a useful reagent in organic synthesis.
^Not recommended: see Blue Book reference.
^This name is also used to refer to tris(dimethylamino)phosphine
^"Front Matter". Nomenclature of Organic Chemistry: IUPAC Recommendations and Preferred Names 2013 (Blue Book). Cambridge: The Royal Society of Chemistry. 2014. pp. P001–P004. doi:10.1039/9781849733069-FP001. ISBN 978-0-85404-182-4.
^ abcdefghNIOSH Pocket Guide to Chemical Hazards. "#0321". National Institute for Occupational Safety and Health (NIOSH).
^Haynes, William M. (2010). Handbook of Chemistry and Physics (91 ed.). Boca Raton, Florida, USA: CRC Press. p. 3-280. ISBN 978-1-43982077-3.
and 23 Related for: Hexamethylphosphoramide information
Hexamethylphosphoramide, often abbreviated HMPA, is a phosphoramide (an amide of phosphoric acid) with the formula [(CH3)2N]3PO. This colorless liquid...
showed that it is possible to replace the suspected carcinogen hexamethylphosphoramide (HMPA) with DMPU. Nomenclature of Organic Chemistry : IUPAC Recommendations...
dimethylformamide, dimethylacetamide, N-methyl-2-pyrrolidone, and hexamethylphosphoramide (HMPA). DMSO is frequently used as a solvent for chemical reactions...
DuPont (Fibre B) as Dupont initially used the carcinogenic HMPT (hexamethylphosphoramide). Despite heavy research DuPont now also applies the AKZO patent...
mechanical drawing orients the polymer chains in the fiber's direction. Hexamethylphosphoramide (HMPA) was the solvent initially used for the polymerization, but...
agriculture to enhance the effectiveness of urea-based fertilizers. Hexamethylphosphoramide (HMPA) is a polar solvent. "Phosphoramide". IUPAC GoldBook. Steger...
called phosphoramides. An example compound is the polar solvent hexamethylphosphoramide (HMPA). Perrin, D. D., ed. (1982) [1969]. Ionisation Constants...
of carbonyls is a system with molybdenum peroxide, pyridine and hexamethylphosphoramide. A family of stereoselective syntheses oxidizes in situ enols with...
water. Another way to make it is with polysulfide dissolved in hexamethylphosphoramide where it gives a blue colour. Other methods of production of S−3...
liquid ammonia or other donor solvents like aliphatic amines or hexamethylphosphoramide to give blue solutions. These solutions are believed to contain...
diethyl ether (Et2O), tetramethylethylene diamine (TMEDA) or hexamethylphosphoramide (HMPA). Methyllithium is a special case: its tetrameric structure...
common application is for alkylation of aldehydes and ketones: Hexamethylphosphoramide a phosphoramide; useful polar aprotic solvent and additive in organic...
some small primary amines, such as methylamine and ethylamine and hexamethylphosphoramide, forming blue solutions. THF dissolves alkali metal, but a Birch...
tetramethylurea is often used as a replacement for the carcinogenic hexamethylphosphoramide (HMPT). Tetramethylurea is suitable as a reaction medium for the...
used as solvents include liquid ammonia, ethyl amine, diglyme, or hexamethylphosphoramide. The choice of solvent depends on the temperature desired, whether...
used to reductively cleave α-keto sulfones; in the presence of hexamethylphosphoramide (HMPA), SmI2 is able to effect reductive elimination of α-functionalized...
UBr5L are known with such ligands as triphenylphosphine oxide and hexamethylphosphoramide, and are obtained by brominating UBr4 in the presence of the desired...
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