Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references
Chemical compound
Gadolinium acetylacetonate is a coordination compound with the formula Gd(C5H7O2)3. This anhydrous acetylacetonate complex is widely discussed but unlikely to exist per se. The 8-coordinated dihydrate Gd(C5H7O2)3(H2O)2 is a more plausible formula based on the behavior of other lathanide complexes. It has also been characterized twice by X-ray crystallography.[2][3]
Upon heating under vacuum, the dihydrate converts to the oxo-cluster Gd4O(C5H7O2)10. This behavior is also observed for europium acetylacetonate, yttrium acetylacetonate, lanthanum acetylacetonate, and erbium acetylacetonate.[4]
Gadoliniumacetylacetonate is a coordination compound with the formula Gd(C5H7O2)3. This anhydrous acetylacetonate complex is widely discussed but unlikely...
is also observed for gadoliniumacetylacetonate, yttrium acetylacetonate, lanthanum acetylacetonate, and erbium acetylacetonate. The electronic structure...
is also observed for gadoliniumacetylacetonate, europium acetylacetonate, lanthanum acetylacetonate, and erbium acetylacetonate. Jantsch, G.; Meyer,...
Lanthanum acetylacetonate refers to the coordination complex with the formula La(C5H7O2)3. This anhydrous acetylacetonate complex has not been characterized...
isotopes of samarium (Sm) and the primary products after are isotopes of gadolinium (Gd). Europium is produced by nuclear fission, but the fission product...
been used in conjunction with sodium acetate. The use of platinum(II) acetylacetonate has also been reported. Several barium platinides have been synthesized...
weakly (the one trans to the vanadyl center). An example is vanadyl acetylacetonate (V(O)(O2C5H7)2). In this complex, the vanadium is 5-coordinate, distorted...
higher energy levels. Lipophilic europium complexes often feature acetylacetonate-like ligands, e.g., Eufod. Europium(II) oxide can be obtained by the...
Epoxidation by means of tertiary butylhydroperoxide (tbhp) and Vanadyl acetylacetonate gives affords exclusively the β-epoxide [82544-13-6] (3). The remaining...