Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references
Chemical compound
Ethyl propiolate is an organic compound with the formula HC2CO2C2H5. It is the ethyl ester of propiolic acid, the simplest acetylenic carboxylic acid. It is a colorless liquid that is miscible with organic solvents. The compound is a reagent and building block for the synthesis of other organic compounds, reactions that exploit the electrophilicity of the alkyne group.[1]
^Dennis E. Vogel; George H. Büchi (1988). "α-Unsubstituted γ,δ-Unsaturated Aldehydes by Claisen Rearrangement: 3-phenyl-4-pentenal". Org. Synth. 66: 29. doi:10.15227/orgsyn.066.0029.
Ethylpropiolate is an organic compound with the formula HC2CO2C2H5. It is the ethyl ester of propiolic acid, the simplest acetylenic carboxylic acid....
cuprous chloride. Propiolates are esters or salts of propiolic acid. Common examples include methyl propiolate and ethylpropiolate. Propargyl Propargyl...
the Favorskii reaction. Illustrative is the sequence shown below, ethylpropiolate is deprotonated by n-butyllithium to give the corresponding lithium...
It can also be prepared synthetically from 1-octyn-3-ol or from ethylpropiolate. Ethyl decadienoate is used in natural flavors and fragrances for its...
(scheme 1), the alkyne proton of ethylpropiolate is deprotonated by n-butyllithium at -78 °C to form lithium ethylpropiolate to which cyclopentanone is added...
The molecular formula C5H6O2 (molar mass: 98.10 g/mol) may refer to: Ethylpropiolate Furfuryl alcohol Glutaconaldehyde Tulipalin A 1,2-Cyclopentanedione...
material. Mono-methylation was conducted followed by a reaction with ethylpropiolate in the presence of ZnCl2 to yield 7-hydroxy-5-methoxycoumarin (product 3...
employing as component parts ammonium acetate, two equivalents of methyl propiolate, and one of 3-nitrobenzaldehyde. Oxidation of the resulting dihydropyridine...
reaction can be generated through the Flash Vacuum Pyrolysis of phenyl propiolate. In organometallic chemistry, azulene serves as a ligand for low-valent...
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