Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Chemical compound
Dirhenium decacarbonyl is the inorganic compound with the chemical formula Re2(CO)10 . Commercially available, it is used as a starting point for the synthesis of many rhenium carbonyl complexes. It was first reported in 1941 by Walter Hieber, who prepared it by reductive carbonylation of rhenium.[2] The compound consists of a pair of square pyramidal Re(CO)5 units joined via a Re-Re bond, which produces a homoleptic carbonyl complex.[3]
^"Dirhenium decacarbonyl". Sigma Aldrich.
^W. Hieber; H. Fuchs (1941). "Über Metallcarbonyle. XXXVIII. Über Rheniumpentacarbonyl". Zeitschrift für anorganische und allgemeine Chemie (in German). 248 (3): 256–268. doi:10.1002/zaac.19412480304.
^F. Armstrong; J. Rourke; M. Hagerman; M. Weller; P. Atkins; T. Overton (2010). "Shiver and Atkins' Inorganic Chemistry 5th edition": 555. {{cite journal}}: Cite journal requires |journal= (help)
and 13 Related for: Dirhenium decacarbonyl information
Dirheniumdecacarbonyl is the inorganic compound with the chemical formula Re2(CO)10 . Commercially available, it is used as a starting point for the synthesis...
about, and synthesis of, dimanganese decacarbonyl was fundamentally guided by the previously known dirheniumdecacarbonyl (Re2(CO)10), the heavy atom analogue...
carbide, silicon carbide, titanium diboride or zirconium diboride. Dirheniumdecacarbonyl is the most common entry to organorhenium chemistry. Its reduction...
the reducing agent. In this way, Hieber and Fuchs first prepared dirheniumdecacarbonyl from the oxide: Re2O7 + 17 CO → Re2(CO)10 + 7 CO2 If metal oxides...
forms aquo-carbonyl complexes, prominent being [Tc(CO)3(H2O)3]+. Dirheniumdecacarbonyl is the most common entry to organorhenium chemistry. Its reduction...
weak acid and represents one of the most important derivatives of dirheniumdecacarbonyl (Re2(CO)10). It is synthesized by treating a methanolic solution...
coexistence of oxide and organic ligands in the same coordination sphere. Dirheniumdecacarbonyl is a common entry point to other rhenium carbonyls. The general...
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