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Diphosphorus information


Diphosphorus
Stick model of diphosphorus
Stick model of diphosphorus
Spacefill model of diphosphorus
Spacefill model of diphosphorus
Names
IUPAC name
Diphosphorus
Systematic IUPAC name
Diphosphyne[1]
Identifiers
CAS Number
  • 12185-09-0 checkY
3D model (JSmol)
  • Interactive image
ChEBI
  • CHEBI:33472 checkY
ChemSpider
  • 4574176 checkY
Gmelin Reference
1400241
PubChem CID
  • 5460700
CompTox Dashboard (EPA)
  • DTXSID301027109 Edit this at Wikidata
InChI
  • InChI=1S/P2/c1-2 checkY
    Key: FOBPTJZYDGNHLR-UHFFFAOYSA-N checkY
  • InChI=1/P2/c1-2
    Key: FOBPTJZYDGNHLR-UHFFFAOYAU
SMILES
  • P#P
Properties
Chemical formula
P2
Molar mass 61.947523996 g·mol−1
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references

Diphosphorus is an inorganic chemical with the chemical formula P
2
. Unlike nitrogen, its lighter pnictogen neighbor which forms a stable N2 molecule with a nitrogen to nitrogen triple bond, phosphorus prefers a tetrahedral form P4 because P-P pi-bonds are high in energy. Diphosphorus is, therefore, very reactive with a bond-dissociation energy (117 kcal/mol or 490 kJ/mol) half that of dinitrogen. The bond distance has been measured at 1.8934 Å.[2]

  1. ^ Cite error: The named reference EBI was invoked but never defined (see the help page).
  2. ^ Cite error: The named reference Herzberg was invoked but never defined (see the help page).

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Diphosphorus

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diphosphorus from a diphosphorus bisanthracene adduct has been reported. The synthesis of a stabilized HP2+ cation has been reported. "Diphosphorus (CHEBI:33472)"...

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Diphosphorus tetraiodide

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subhalide of phosphorus. It is the most stable of the diphosphorus tetrahalides. Diphosphorus tetraiodide is easily generated by the disproportionation...

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Allotropes of phosphorus

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violet and black allotropes are also known. Gaseous phosphorus exists as diphosphorus and atomic phosphorus. White phosphorus, yellow phosphorus or simply...

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Diphosphorus tetrafluoride

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PF3•BH3 and a polymer with formula PF. Diphosphorus tetrafluoride reacts with oxygen or water to yield diphosphorus tetrafluoride oxide, which has one oxygen...

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Diphosphorus tetrachloride

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Diphosphorus tetrachloride is an inorganic compound with a chemical formula P2Cl4. It is a colorless liquid that decomposes near room temperature and ignites...

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Diphosphorus trisulfide

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Diphosphorus trisulfide (sometimes called phosphorus trisulfide) is a phosphorus sulfide with the formula of P2S3. The substance is highly unstable and...

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Triple bond

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bond are cyanides and isocyanides. Some diatomic molecules, such as diphosphorus and carbon monoxide, are also triple bonded. In skeletal formulae the...

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Phosphorus pentasulfide

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Other names Phosphorus sulfide Sulfur phosphide Phosphorus persulfide Diphosphorus pentasulfide Tetraphosphorus decasulfide Phosphorus decasulfide Identifiers...

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Phosphorus trioxide

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phosphoryl halide, and it reacts with iodine in a sealed tube to form diphosphorus tetraiodide. P4O6 reacts with ozone at 195 K to give the unstable compound...

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Phosphorus sulfides

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phosphorus with sulfur above 570 K in an evacuated tube. P4 + 10 S → P4S10 Diphosphorus trisulfide (P2S3) Jason, M. E.; Ngo, T.; Rahman, S. (1997). "Products...

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Phosphorus pentoxide

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7λ5-tetraphosphatricyclo[3.3.1.13,7]decane 1,3,5,7-tetraoxide Other names Diphosphorus pentoxide Phosphorus(V) oxide Phosphoric anhydride Tetraphosphorus decaoxide...

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Phosphorus tetroxide

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Diphosphorus tetroxide, or phosphorus tetroxide is an inorganic compound of phosphorus and oxygen. It has the empirical chemical formula P2O4. Solid phosphorus...

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Chemical trap

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(ceric ammonium nitrate) and the trapping agent be mutually compatible. Diphosphorus is an old target of chemists since it is the heavy analogue of N2. Its...

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Phosphorus

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soluble in carbon disulfide. Thermal decomposition of P4 at 1100 K gives diphosphorus, P2. This species is not stable as a solid or liquid. The dimeric unit...

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Phosphorus halide

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syntheses, the others are of purely academic interest at the present time. Diphosphorus tetrabromide is particularly poorly described. They are subhalides of...

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Phosphorus fluoride

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following: Phosphorus trifluoride, PF3 Phosphorus pentafluoride, PF5 Diphosphorus tetrafluoride, P2F4 See phosphorus halides for a complete list of phosphorus...

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Diatomic molecule

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repolymerize when cooled. Heating ("cracking") elemental phosphorus gives diphosphorus (P2). Sulfur vapor is mostly disulfur (S2). Dilithium (Li2) and disodium...

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Phenanthrene

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electrophilic aromatic substitution using a tethered cyclohexanol group using diphosphorus pentoxide, which closes the central ring onto an existing aromatic ring...

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M5 fiber

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polymerization between tetraaminopyridine and dihydroxyterephthalic acid using diphosphorus pentoxide as a dehydrating agent. The polymer mixture is then heated...

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P2

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management strategy emphasizing avoiding waste rather than treating it Diphosphorus (P 2), an inorganic chemical SARS-CoV-2 Zeta variant, one of the variants...

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Chemical nomenclature

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nitrogen trichloride, BF3 is termed boron trifluoride, and P2O5 is termed diphosphorus pentoxide (although the a of the prefix penta- should actually not be...

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Hydrazine

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compounds Other anions Tetrafluorohydrazine Hydrogen peroxide Diphosphane Diphosphorus tetraiodide Other cations Organic hydrazines Related Binary azanes Ammonia...

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Phosphorus triiodide

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reactions, and for the preparation of Grignard reagents. Nitrogen triiodide Diphosphorus tetraiodide Phosphorus trifluoride Phosphorus trichloride Phosphorus...

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Oxidation state

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Schleyer, Paul v. R.; Robinson, Gregory H. (2008). "Carbene-Stabilized Diphosphorus". Journal of the American Chemical Society. 130 (45): 14970–1. doi:10...

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Organophosphorus chemistry

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Schleyer, Paul v. R.; Robinson, Gregory H. (2008). "Carbene-Stabilized Diphosphorus". Journal of the American Chemical Society. 130 (45): 14970–1. doi:10...

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Phosphorus trisulfide

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Phosphorus trisulfide may refer to: Phosphorus sesquisulfide Diphosphorus trisulfide This set index article lists chemical compounds articles associated...

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Diphosphane

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Related Binary Phosphorus halides diphosphorus tetrafluoride diphosphorus tetrachloride diphosphorus tetrabromide diphosphorus tetraiodide Related compounds...

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Allotropy

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crystalline structure Black phosphorus – semiconductor, analogous to graphite Diphosphorus – gaseous form composed of P2 molecules, stable between 1200 °C and 2000 °C;...

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Glossary of chemical formulae

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10025-87-3 P2I4 diphosphorus tetraiodide 13455-00-0 P2O5 phosphorus pentoxide 1314-56-3 P2S3 diphosphorus trisulfide 12165-69-4 P2Se3 diphosphorus triselenide...

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IUPAC nomenclature of inorganic chemistry

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of phosphorus is called phosphorus pentaoxide. It should actually be diphosphorus pentaoxide, but it is assumed that there are two phosphorus atoms (P2O5)...

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