Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Chemical compound
Dioxygenyl hexafluoroplatinate is a compound with formula O2PtF6. It is a hexafluoroplatinate of the unusual dioxygenyl cation, O2+, and is the first known compound containing this cation.[1] It can be produced by the reaction of dioxygen with platinum hexafluoride. The fact that PtF 6 is strong enough to oxidise O 2, whose first ionization potential is 12.2 eV, led Neil Bartlett to correctly surmise that it might be able to oxidise xenon (first ionization potential 12.13 eV). This led to the discovery of xenon hexafluoroplatinate,[2] which proved that the noble gases, previously thought to be inert, are able to form chemical compounds.
^Cite error: The named reference bartlett1962 was invoked but never defined (see the help page).
^Bartlett, Neil (1962). "Xenon hexafluoroplatinate(V), Xe+ [PtF 6]− ". Proc. Chem. Soc.: 197–236. doi:10.1039/PS9620000197.
and 11 Related for: Dioxygenyl hexafluoroplatinate information
Dioxygenylhexafluoroplatinate is a compound with formula O2PtF6. It is a hexafluoroplatinate of the unusual dioxygenyl cation, O2+, and is the first...
molecules. Neil Bartlett demonstrated that dioxygenylhexafluoroplatinate (O2PtF6), containing the dioxygenyl cation, can be prepared at room temperature...
and oxygen formed a red solid. The red solid turned out to be dioxygenylhexafluoroplatinate, O+ 2[PtF6]−. Bartlett noticed that the ionization energy for...
oxidizing agent that could oxidize oxygen gas (O2) to form dioxygenylhexafluoroplatinate (O+ 2[PtF 6]− ). Since O2 (1165 kJ/mol) and xenon (1170 kJ/mol)...
6 had been shown to react with oxygen to form [O2]+[PtF6]−, dioxygenylhexafluoroplatinate. Hexafluoride Chloroplatinic acid Drews, T.; Supel, J.; Hagenbach...
by-product when dioxygenylhexafluoroplatinate is used to prepare other platinum(V) compounds such as potassium hexafluoroplatinate(V), using potassium...
unstable compound Kr(OTeF5)2. One unexpected oxygen compound is dioxygenylhexafluoroplatinate, O+ 2PtF− 6, discovered in studying the properties of platinum...
occurs with PtF 6, which oxidizes oxygen to give O2+PtF6−, dioxygenylhexafluoroplatinate. Among the most important classes of organic compounds that...
ISBN 978-0-444-20528-5. Bartlett, Neil; Lohmann, D. H. (1962). "Dioxygenylhexafluoroplatinate (V), O2+[PtF6]−". Proceedings of the Chemical Society (3): 115...
to form dioxygenylhexafluoroplatinate, and for being the first compound that was observed to react with xenon (see xenon hexafluoroplatinate). Some metal...
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