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Diamine information



General structure of (primary) diamines. The primary amino groups (NH2) are marked blue,
R is a divalent organic radical (e.g. a para-phenylene group).

A diamine is an amine with exactly two amino groups. Diamines are used as monomers to prepare polyamides, polyimides, and polyureas. The term diamine refers mostly to primary diamines, as those are the most reactive.[1]

In terms of quantities produced, 1,6-diaminohexane (a precursor to Nylon 6-6) is most important, followed by ethylenediamine.[2] Vicinal diamines (1,2-diamines) are a structural motif in many biological compounds and are used as ligands in coordination chemistry.[3]

  1. ^ "Nucleophilicity Trends of Amines". Master Organic Chemistry. 2018-05-07. Retrieved 2019-08-18.
  2. ^ Karsten Eller; Erhard Henkes; Roland Rossbacher; Hartmut Höke (2005). "Amines, Aliphatic". Ullmann's Encyclopedia of Industrial Chemistry. Weinheim: Wiley-VCH. doi:10.1002/14356007.a02_001. ISBN 3-527-30673-0.
  3. ^ Lucet, D., Le Gall, T. and Mioskowski, C. (1998), The Chemistry of Vicinal Diamines. Angew. Chem. Int. Ed., 37: 2580–2627. doi:10.1002/(SICI)1521-3773(19981016)37:19<2580::AID-ANIE2580>3.0.CO;2-L

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Diamine

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diamine is an amine with exactly two amino groups. Diamines are used as monomers to prepare polyamides, polyimides, and polyureas. The term diamine refers...

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Diamine oxidase

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Diamine oxidase (DAO), also known "amine oxidase, copper-containing, 1" (AOC1), formerly called histaminase, is an enzyme (EC 1.4.3.22) involved in the...

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Silver diammine fluoride

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Silver diammine fluoride (SDF), also known as silver diamine fluoride in most of the dental literature, (although this is a chemical misnomer) is a topical...

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Hexamethylenediamine

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Hexamethylenediamine or hexane-1,6-diamine, is the organic compound with the formula H2N(CH2)6NH2. The molecule is a diamine, consisting of a hexamethylene...

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Isophorone diamine

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Isophorone diamine (usually shortened to IPDA) is a chemical compound and specifically a diamine with the formula (CH3)3C6H7(NH2)(CH2NH2). It is a colorless...

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Ethylenediaminetetraacetic acid

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2′′,2′′′-(Ethane-1,2-diyldinitrilo)tetraacetic acid Other names EthyleneDiamineTetraAcetic acid Diaminoethane-tetraacetic acid Edetic acid (conjugate base...

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Diamine transaminase

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In enzymology, a diamine transaminase (EC 2.6.1.29) is an enzyme that catalyzes the chemical reaction: an alpha,omega-diamine + 2-oxoglutarate ⇌ {\displaystyle...

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Cadaverine

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is an organic compound with the formula (CH2)5(NH2)2. Classified as a diamine, it is a colorless liquid with an unpleasant odor. It is present in small...

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Ethylenediamine

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Ethylenediamine Names Preferred IUPAC name Ethane-1,2-diamine Other names Edamine, 1,2-Diaminoethane, 'en' when a ligand Identifiers CAS Number 107-15-3 Y...

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Isophorone diisocyanate

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reaction create mixture of isophorone diamine conformers (25% cis, 75% trans). Reaction of isophorone diamine with phosgene to form isophorone diisocyanate...

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Putrescine

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colorless solid that melts near room temperature. It is classified as a diamine. Together with cadaverine, it is largely responsible for the foul odor...

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Histamine

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inactivated by its primary degradative enzymes, histamine-N-methyltransferase or diamine oxidase. In the central nervous system, histamine released into the synapses...

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FKM

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cross-linking mechanisms used in the curing process of FKMs. Diamine cross-linking using a blocked diamine. In the presence of basic (alkaline) media, VDF is vulnerable...

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Tetramethylethylenediamine

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TMEDA adduct of lithium bis(trimethylsilyl)amide Notice that the diamine is a bidentate ligand....

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Toluenediamine

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Toluenediamine may refer to these isomeric organic compounds with the formula C6H3(NH2)2(CH3): 2,4-Diaminotoluene, precursor to toluene diisocyanate and...

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Methylene diphenyl diisocyanate

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4'-Methylenedianiline and other diamine precursors, as well as their corresponding polyamines: Then, these diamines are treated with phosgene to form...

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Phenylenediamine

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Look up phenylenediamine in Wiktionary, the free dictionary. Phenylenediamine may refer to: o-phenylenediamine or OPD, a chemical compound C6H4(NH2)2 m-phenylenediamine...

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Diethyl toluene diamine

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Diethyl toluene diamine (DETDA) is a liquid aromatic organic molecule with formula C11H18N2. It is chemically an aromatic diamine and has the CAS Registry...

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Histamine intolerance

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from reduced activity or levels of the enzymes that metabolize histamine: diamine oxidase (DAO) and histamine N-methyltransferase (HNMT). Still, the exact...

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Ethylenedinitramine

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name N,N′-Dinitro-1,2-ethanediamine Other names Haleite; Dinitroethylene diamine; EDNA Identifiers CAS Number 505-71-5 3D model (JSmol) Interactive image...

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Benzidine

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Benzidine (trivial name), also called 1,1'-biphenyl-4,4'-diamine (systematic name), is an organic compound with the formula (C6H4NH2)2. It is an aromatic...

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Ethylenediamine pyrocatechol

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Ethylenediamine pyrocatechol (EDP), also known as ethylenediamine-pyrocatechol-water (EPW), is an anisotropic etchant solution for silicon. A typical formulation...

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Polyetheramines

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(2021-08-01). "The Curing Kinetics Analysis of Four Epoxy Resins Using a Diamine Terminated Polyether as Curing Agent". Thermochimica Acta. 702: 178987...

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