The principle of detailed balance can be used in kinetic systems which are decomposed into elementary processes (collisions, or steps, or elementary reactions). It states that at equilibrium, each elementary process is in equilibrium with its reverse process.
The principle of detailedbalance can be used in kinetic systems which are decomposed into elementary processes (collisions, or steps, or elementary reactions)...
are somewhere between detailedbalance and global balance equations. Any solution π {\displaystyle \pi } to the local balance equations is always a solution...
reversibility), the kinetic theory is also connected to the principle of detailedbalance, in terms of the fluctuation-dissipation theorem (for Brownian motion)...
cannot be affected by the presence or absence of other excited atoms. Detailedbalance (valid only at equilibrium) requires that the change in time of the...
probability theory, the probability m for the stochastic matrix obeys detailedbalance when the stationary distribution ρ n {\displaystyle \rho _{n}} has...
According to Boltzmann, this microreversibility implies the principle of detailedbalance for collisions: at the equilibrium ensemble each collision is equilibrated...
33%. Values of the detailedbalance limit are available in tabulated form and a MATLAB program for implementing the detailedbalance model has been written...
kinetics, the Onsager relations are closely connected to the principle of detailedbalance and follow from them in the linear approximation near equilibrium....
is an alternative to Metropolis–Hastings, which doesn't satisfy the detailedbalance condition. Barker's algorithm does converge to the target distribution...
Gorban, Yablonsky developed the theory of chemical thermodynamics and detailedbalance in the limit of irreversible reactions. A simple scheme for the nonlinear...
forward and backward reactions are equal, a principle called detailedbalance. Detailedbalance is a property of the stoichiometric matrix N i j {\displaystyle...
A_{kk}P_{k}=-\sum _{\ell \neq k}(A_{\ell k}P_{k}).} The master equation exhibits detailedbalance if each of the terms of the summation disappears separately at equilibrium—i...
Physical Review.[citation needed] In 1952 he proved the principle of semi-detailedbalance for kinetics without microscopic reversibility. In 1953 he and the...
theoretical limit for an IB device with one midgap energy level using detailedbalance. They assumed no carriers were collected at the IB and that the device...
defined for any Markov processes with reversible dynamics and the detailedbalance property. In Boltzmann's 1896 Lectures on Gas Theory, he showed that...
in state μ. It then uses acceptance probabilities A(μ, ν) so that detailedbalance is satisfied. If the new state ν is accepted, then we move to that...
same distribution, as long as the algorithm satisfies ergodicity and detailedbalance. In both algorithms, for any change in energy, p ( Δ E ) ≠ 0 {\displaystyle...
in part alleviated by using multiple junction implementations). The detailedbalance calculation shows that this efficiency can not exceed 33% if one uses...
they would also have to emit them in the right amount to maintain detailedbalance. Time-independent solutions to field equations do not emit radiation...
reversibility. Roughly speaking, this property, also called the principle of detailedbalance, means that the probabilities to traverse a given path in one direction...