A dearomatization reaction is an organic reaction in which the reactants are arenes and the products permanently lose their aromaticity.[1] It is of some importance in synthetic organic chemistry for the organic synthesis of new building blocks [1] and in total synthesis.[2] Types of carbocyclic arene dearomization include hydrogenative (Birch reduction), alkylative, photochemical, thermal, oxidative, transition metal-assisted and enzymatic.[1]
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and 13 Related for: Dearomatization reaction information
of transition metal-assisted dearomatization is the Buchner ring expansion. Catalytic asymmetric dearomatizationreactions (CADA) are used in enantioselective...
synthesis and are involved in many reaction types, following both additions and removals, as well as saturation and dearomatization. Heteroarenes are closely related...
Aromatization is a chemical reaction in which an aromatic system is formed from a single nonaromatic precursor. Typically aromatization is achieved by...
(2022-03-14). "Modulating the Frontier Orbitals of an Aluminylene for Facile Dearomatization of Inert Arenes**". Angewandte Chemie International Edition. 61 (12):...
Benjamin K.; Harman, W. Dean (2017). "Group 6 Dihapto-Coordinate Dearomatization Agents for Organic Synthesis". Chemical Reviews. 117 (22): 13721–13755...
The two most common problems in this class of reactions are low ortho/para selectivities and dearomatization (the latter is a particularly significant problem...
useful tool for the physical organic chemist is the metal-catalyzed dearomatization of benzene. Chromium tricarbonyl is highly electrophilic due to the...
have been used as electrophiles in synthetic organic chemistry to build dearomatized congeners called dihydropyridines, as demonstrated in one example from...
respectively. The key step of this synthesis was the Nickel catalyzed dearomatization of benzene which directly installed the amine and catachol ring in...
syn-1,2-Carboboration and -Silylation: Alkene Scope, Applications in Dearomatization, and Stereocontrol via a Chiral Auxiliary". Angewandte Chemie International...
5-dienes ("dihydrodiols"). The oxidation of aromatic compounds to dearomatized products is a step in the processing of arenes. Since seminal study by...
from various homogeneous catalysis reactions, including the dehydrogenating coupling of stannanes, H-transfer reactions and ethylene oligomerization, to...
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