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Axial cross section of Carnot's heat engine. In this diagram, abcd is a cylindrical vessel, cd is a movable piston, and A and B are constant–temperature bodies. The vessel may be placed in contact with either body or removed from both (as it is here).[1]
A Carnot heat engine[2] is a theoretical heat engine that operates on the Carnot cycle. The basic model for this engine was developed by Nicolas Léonard Sadi Carnot in 1824. The Carnot engine model was graphically expanded by Benoît Paul Émile Clapeyron in 1834 and mathematically explored by Rudolf Clausius in 1857, work that led to the fundamental thermodynamic concept of entropy. The Carnot engine is the most efficient heat engine which is theoretically possible.[3] The efficiency depends only upon the absolute temperatures of the hot and cold heat reservoirs between which it operates.
A heat engine acts by transferring energy from a warm region to a cool region of space and, in the process, converting some of that energy to mechanical work. The cycle may also be reversed. The system may be worked upon by an external force, and in the process, it can transfer thermal energy from a cooler system to a warmer one, thereby acting as a refrigerator or heat pump rather than a heat engine.
Every thermodynamic system exists in a particular state. A thermodynamic cycle occurs when a system is taken through a series of different states, and finally returned to its initial state. In the process of going through this cycle, the system may perform work on its surroundings, thereby acting as a heat engine.
The Carnot engine is a theoretical construct, useful for exploring the efficiency limits of other heat engines. An actual Carnot engine, however, would be completely impractical to build.
^Figure 1 in Carnot (1824, p. 17) and Carnot (1890, p. 63). In the diagram, the diameter of the vessel is large enough to bridge the space between the two bodies, but in the model, the vessel is never in contact with both bodies simultaneously. Also, the diagram shows an unlabeled axial rod attached to the outside of the piston.
^In French, Carnot uses machine à feu, which Thurston translates as heat-engine or steam-engine. In a footnote, Carnot distinguishes the steam-engine (machine à vapeur) from the heat-engine in general. (Carnot, 1824, p. 5 and Carnot, 1890, p. 43)
^"The Carnot Efficiency | EGEE 102: Energy Conservation and Environmental Protection". www.e-education.psu.edu. Retrieved 2022-01-24.
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