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Calcium oxide information


Calcium oxide
Calcium oxide
Ionic crystal structure of calcium oxide
  Ca2+   O2-

Powder sample of white calcium oxide
Names
IUPAC name
Calcium oxide
Other names
  • Lime
  • Quicklime
  • Burnt lime
  • Unslaked lime
  • Free lime (building)
  • Caustic lime
  • Pebble lime
  • Calcia
  • Oxide of calcium
Identifiers
CAS Number
  • 1305-78-8
3D model (JSmol)
  • Interactive image
ChEBI
  • CHEBI:31344
ChEMBL
  • ChEMBL2104397
ChemSpider
  • 14095
ECHA InfoCard 100.013.763 Edit this at Wikidata
EC Number
  • 215-138-9
E number E529 (acidity regulators, ...)
Gmelin Reference
485425
KEGG
  • C13140
PubChem CID
  • 14778
RTECS number
  • EW3100000
UNII
  • C7X2M0VVNH
UN number 1910
CompTox Dashboard (EPA)
  • DTXSID5029631 Edit this at Wikidata
InChI
  • InChI=1S/Ca.O
    Key: ODINCKMPIJJUCX-UHFFFAOYSA-N
  • InChI=1/Ca.O/rCaO/c1-2
    Key: ODINCKMPIJJUCX-BFMVISLHAU
SMILES
  • O=[Ca]
Properties
Chemical formula
CaO
Molar mass 56.0774 g/mol
Appearance White to pale yellow/brown powder
Odor Odorless
Density 3.34 g/cm3[1]
Melting point 2,613 °C (4,735 °F; 2,886 K)[1]
Boiling point 2,850 °C (5,160 °F; 3,120 K) (100 hPa)[2]
Solubility in water
Reacts to form calcium hydroxide
Solubility in Methanol Insoluble (also in diethyl ether, octanol)
Acidity (pKa) 12.8
Magnetic susceptibility (χ)
−15.0×10−6 cm3/mol
Structure
Crystal structure
Cubic, cF8
Thermochemistry
Std molar
entropy (S298)
40 J·mol−1·K−1[3]
Std enthalpy of
formation fH298)
−635 kJ·mol−1[3]
Pharmacology
ATCvet code
QP53AX18 (WHO)
Hazards
GHS labelling:
Pictograms
GHS05: CorrosiveGHS07: Exclamation mark
Signal word
Danger
Hazard statements
H302, H314, H315, H335
Precautionary statements
P260, P261, P264, P270, P271, P280, P301+P312, P301+P330+P331, P302+P352, P303+P361+P353, P304+P340, P305+P351+P338, P310, P312, P321, P330, P332+P313, P362, P363, P403+P233, P405, P501
NFPA 704 (fire diamond)
NFPA 704 four-colored diamondHealth 3: Short exposure could cause serious temporary or residual injury. E.g. chlorine gasFlammability 0: Will not burn. E.g. waterInstability 2: Undergoes violent chemical change at elevated temperatures and pressures, reacts violently with water, or may form explosive mixtures with water. E.g. white phosphorusSpecial hazard W: Reacts with water in an unusual or dangerous manner. E.g. sodium, sulfuric acid
3
0
2
W
Flash point Non-flammable[4]
NIOSH (US health exposure limits):
PEL (Permissible)
TWA 5 mg/m3[4]
REL (Recommended)
TWA 2 mg/m3[4]
IDLH (Immediate danger)
25 mg/m3[4]
Safety data sheet (SDS) ICSC 0409
Related compounds
Other anions
Calcium sulfide
Calcium hydroxide
Calcium selenide
Calcium telluride
Other cations
Beryllium oxide
Magnesium oxide
Strontium oxide
Barium oxide
Radium oxide
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references

Calcium oxide (formula: CaO), commonly known as quicklime or burnt lime, is a widely used chemical compound. It is a white, caustic, alkaline, crystalline solid at room temperature. The broadly used term lime connotes calcium-containing inorganic compounds, in which carbonates, oxides, and hydroxides of calcium, silicon, magnesium, aluminium, and iron predominate. By contrast, quicklime specifically applies to the single compound calcium oxide. Calcium oxide that survives processing without reacting in building products, such as cement, is called free lime.[5]

Quicklime is relatively inexpensive. Both it and the chemical derivative calcium hydroxide (of which quicklime is the base anhydride) are important commodity chemicals.

  1. ^ a b Haynes, William M., ed. (2011). CRC Handbook of Chemistry and Physics (92nd ed.). Boca Raton, FL: CRC Press. p. 4.55. ISBN 1-4398-5511-0.
  2. ^ Calciumoxid Archived 2013-12-30 at the Wayback Machine. GESTIS database
  3. ^ a b Zumdahl, Steven S. (2009). Chemical Principles 6th Ed. Houghton Mifflin Company. p. A21. ISBN 978-0-618-94690-7.
  4. ^ a b c d NIOSH Pocket Guide to Chemical Hazards. "#0093". National Institute for Occupational Safety and Health (NIOSH).
  5. ^ "free lime". DictionaryOfConstruction.com. Archived from the original on 2017-12-09.

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CaCO3), to form calcium oxide, CaO, commonly called quicklime, with reaction enthalpy 178 kJ/mol: CaCO3(s) → CaO(s) + CO2(g) Calcium carbonate reacts...

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Calcium hydroxide

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a colorless crystal or white powder and is produced when quicklime (calcium oxide) is mixed with water. It has many names including hydrated lime, caustic...

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Calcium carbide

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about 80–85% of CaC2 (the rest is CaO (calcium oxide), Ca3P2 (calcium phosphide), CaS (calcium sulfide), Ca3N2 (calcium nitride), SiC (silicon carbide), etc...

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magnesium oxide. Inhalation of magnesium oxide fumes can cause metal fume fever. Calcium oxide – Chemical compound of calcium Barium oxide – Chemical...

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Cement

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by ancient Romans who used volcanic ash (pozzolana) with added lime (calcium oxide). Non-hydraulic cement (less common) does not set in wet conditions...

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It is produced by the reaction of calcium oxide, calcium carbonate with hydrobromic acid or the reaction of calcium metal with elemental bromine. It adopts...

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limestone (calcium carbonate) through combustion to yield calcium oxide (quicklime). This calcination reaction is CaCO3(s) → CaO(s) + CO2(g). Calcium oxide is...

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metal oxides arise by decomposition of other metal compounds, e.g. carbonates, hydroxides, and nitrates. In the making of calcium oxide, calcium carbonate...

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fed by oxygen and hydrogen is directed at a cylinder of quicklime (calcium oxide), which can be heated to 2,572 °C (4,662 °F) before melting. The light...

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fruit Lime (material), inorganic materials containing calcium, usually calcium oxide or calcium hydroxide Lime (color), a color between yellow and green...

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Sodium oxide

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manufactured glass contains around 15% sodium oxide, 70% silica (silicon dioxide), and 9% lime (calcium oxide). The sodium carbonate "soda" serves as a flux...

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intercalation hosts proposed transition metal oxides and sulfides. The study of calcium batteries as well as calcium electro-chemistry continued. Research expanded...

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ash, calcium oxide, and salt is included in the plastering mixture, thereby increasing its pH and sodium content. The addition of calcium oxide and wood...

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and its oxide form (MO) to separate carbon dioxide from other gases coming from either power generation or an industrial plant. In the calcium looping...

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Sulfation

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the presence of calcium oxide or calcium carbonate, which, directly or indirectly, bind sulfur dioxide and some oxygen to give calcium sulfite. The net...

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Calcium phosphate

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inorganic phosphate anions. Some so-called calcium phosphates contain oxide and hydroxide as well. Calcium phosphates are white solids of nutritional...

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Slag

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better suited as an aggregate. It may also have higher free calcium oxide and magnesium oxide content, which are often converted to its hydrated forms if...

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example lead as lead oxide. Boron is considered by many to be a glass former rather than a flux. Some oxides, such as calcium oxide, flux significantly...

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alumina Aerogel Benzophenone (as anion) Bentonite clay Calcium chloride Calcium oxide Calcium sulfate (Drierite) Cobalt(II) chloride Copper(II) sulfate...

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strontium oxide and calcium oxide. Another standard formulation is barium oxide, calcium oxide, and aluminium oxide in a 5:3:2 ratio. Thorium oxide may be...

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foodstuffs. It is a white waxy powder. Calcium stearate is produced by heating stearic acid and calcium oxide: 2 C17H35COOH + CaO → (C17H35COO)2Ca + H2O...

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