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Caesium iodide information


Caesium iodide
Caesium iodide
CsI crystal

Scintillating CsI crystal

Crystal structure
Names
IUPAC name
Caesium iodide
Other names
Cesium iodide
Identifiers
CAS Number
  • 7789-17-5 checkY[1]
3D model (JSmol)
  • Interactive image
ChemSpider
  • 23003 checkY
ECHA InfoCard 100.029.223 Edit this at Wikidata
EC Number
  • 232-145-2
PubChem CID
  • 24601
RTECS number
  • FL0350000
UNII
  • U1P3GVC56L
CompTox Dashboard (EPA)
  • DTXSID3064859 Edit this at Wikidata
InChI
  • InChI=1S/Cs.HI/h;1H/q+1;/p-1 checkY
    Key: XQPRBTXUXXVTKB-UHFFFAOYSA-M checkY
  • InChI=1/Cs.HI/h;1H/q+1;/p-1
    Key: XQPRBTXUXXVTKB-REWHXWOFAA
SMILES
  • [Cs+].[I-]
Properties
Chemical formula
CsI
Molar mass 259.809 g/mol[2]
Appearance white crystalline solid
Density 4.51 g/cm3[2]
Melting point 632 °C (1,170 °F; 905 K)[2]
Boiling point 1,280 °C (2,340 °F; 1,550 K)[2]
Solubility in water
848 g/L (25 °C)[2]
Magnetic susceptibility (χ)
-82.6·10−6 cm3/mol[3]
Refractive index (nD)
1.9790 (0.3 µm)
1.7873 (0.59 µm)
1.7694 (0.75 µm)
1.7576 (1 µm)
1.7428 (5 µm)
1.7280 (20 µm)[4]
Structure
Crystal structure
CsCl, cP2
Space group
Pm3m, No. 221[5]
Lattice constant
a = 0.4503 nm
Lattice volume (V)
0.0913 nm3
Formula units (Z)
1
Coordination geometry
Cubic (Cs+)
Cubic (I)
Thermochemistry
Heat capacity (C)
52.8 J/mol·K[6]
Std molar
entropy (S298)
123.1 J/mol·K[6]
Std enthalpy of
formation fH298)
−346.6 kJ/mol[6]
Gibbs free energy fG)
-340.6 kJ/mol[6]
Hazards
GHS labelling:
Pictograms
GHS07: Exclamation markGHS08: Health hazardGHS09: Environmental hazard
Signal word
Warning
Hazard statements
H315, H317, H319, H335
Precautionary statements
P201, P202, P261, P264, P270, P271, P272, P273, P280, P281, P301+P312, P302+P352, P304+P340, P305+P351+P338, P308+P313, P312, P321, P330, P332+P313, P333+P313, P337+P313, P362, P363, P391, P403+P233, P405, P501
Flash point Non-flammable
Lethal dose or concentration (LD, LC):
LD50 (median dose)
2386 mg/kg (oral, rat)[1]
Related compounds
Other anions
Caesium fluoride
Caesium chloride
Caesium bromide
Caesium astatide
Other cations
Lithium iodide
Sodium iodide
Potassium iodide
Rubidium iodide
Francium iodide
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
checkY verify (what is checkY☒N ?)
Infobox references

Caesium iodide or cesium iodide (chemical formula CsI) is the ionic compound of caesium and iodine. It is often used as the input phosphor of an X-ray image intensifier tube found in fluoroscopy equipment. Caesium iodide photocathodes are highly efficient at extreme ultraviolet wavelengths.[7]

  1. ^ a b Cesium iodide. U.S. National Library of Medicine
  2. ^ a b c d e Haynes, p. 4.57
  3. ^ Haynes, p. 4.132
  4. ^ Haynes, p. 10.240
  5. ^ Huang, Tzuen-Luh; Ruoff, Arthur L. (1984). "Equation of state and high-pressure phase transition of CsI". Physical Review B. 29 (2): 1112. Bibcode:1984PhRvB..29.1112H. doi:10.1103/PhysRevB.29.1112.
  6. ^ a b c d Haynes, p. 5.10
  7. ^ Kowalski, M. P.; Fritz, G. G.; Cruddace, R. G.; Unzicker, A. E.; Swanson, N. (1986). "Quantum efficiency of cesium iodide photocathodes at soft x-ray and extreme ultraviolet wavelengths". Applied Optics. 25 (14): 2440. Bibcode:1986ApOpt..25.2440K. doi:10.1364/AO.25.002440. PMID 18231513.

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Caesium iodide

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Caesium iodide or cesium iodide (chemical formula CsI) is the ionic compound of caesium and iodine. It is often used as the input phosphor of an X-ray...

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rotational quantum numbers, Jodd) are measurable. Caesium iodide and thallium-doped sodium iodide are used in crystal scintillators for the detection...

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2012-12-18 at the Wayback Machine, IR transmission spectrum Ultra-violet photoabsorption measurements in alkali iodide and caesium bromide evaporated films...

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Caesium chloride

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Caesium chloride or cesium chloride is the inorganic compound with the formula CsCl. This colorless salt is an important source of caesium ions in a variety...

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Scandium triiodide

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used in metal halide lamps together with similar compounds, such as caesium iodide, because of their ability to maximize emission of UV and to prolong...

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Explorer 4

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electrons (E>700 keV) and protons (E>10 MeV), a shielded directional caesium iodide scintillation counter sensitive to electrons (E>20 keV) and protons...

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Fluoroscopy

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minimizing the radiation dose to the patient. Modern fluoroscopes use caesium iodide (CsI) screens and produce noise-limited images, ensuring that the minimal...

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Lithium iodide

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Lithium iodide, or LiI, is a compound of lithium and iodine. When exposed to air, it becomes yellow in color, due to the oxidation of iodide to iodine...

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Caesium fluoride

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Caesium fluoride (cesium fluoride in American English) is an inorganic compound with the formula CsF. A hygroscopic white salt, caesium fluoride is used...

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Caesium ozonide

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Caesium ozonide is an oxygen-rich chemical compound of caesium, with the chemical formula CsO3. It consists of caesium cations Cs+ and ozonide anions O−3...

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Digital radiography

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with a scintillator in the detector’s outer layer, which is made from caesium iodide (CsI) or gadolinium oxysulfide (Gd2O2S), converts X-rays to light. Because...

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Argon

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onto frozen argon containing a small amount of hydrogen fluoride with caesium iodide. This discovery caused the recognition that argon could form weakly...

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Sodium iodide

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Sodium iodide (chemical formula NaI) is an ionic compound formed from the chemical reaction of sodium metal and iodine. Under standard conditions, it is...

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Glossary of chemical formulae

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spellings may differ, such as aluminum/aluminium, sulfur/sulphur, and caesium/cesium. Contents A B C Ca–Cu D E F G H I K L M N O P R S T U V W X Y Z...

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List of CAS numbers by chemical compound

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CsI caesium iodide 7789–17–5 CsIO3 caesium iodate 13454–81–4 CsIO4 caesium periodate 13478–04–1 CsMnO4 caesium permanganate 13456–28–5 CsNH2 caesium amide...

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List of inorganic compounds

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Caesium fluoride – CsF Caesium hydride – CsH Caesium hydrogen sulfate – CsHSO4 Caesium iodide – CsI Caesium sulfate – Cs2SO4 Californium(III) bromide –...

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Radiography

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of a vacuum tube with a wide input surface coated on the inside with caesium iodide (CsI). When hit by X-rays material phosphors which causes the photocathode...

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Argon fluorohydride

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chemical was synthesized by mixing argon and hydrogen fluoride on a caesium iodide surface at 8 K (−265 °C), and exposing the mixture to ultraviolet radiation...

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Photocathode

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this photocathode can operate up to 1700 nm. Cs-Te, Cs-I (caesium-telluride, caesium iodide). These materials are sensitive to vacuum UV and UV rays but...

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Rubidium iodide

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Rubidium iodide is a salt of rubidium and iodine, with the chemical formula RbI. It is a white solid with a melting point of 642 °C. Rubidium iodide can be...

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