The Bingel reaction in fullerene chemistry is a fullerene cyclopropanation reaction to a methanofullerene first discovered by C. Bingel in 1993 with the bromo derivative of diethyl malonate in the presence of a base such as sodium hydride or DBU.[1] The preferred double bonds for this reaction on the fullerene surface are the shorter bonds at the junctions of two hexagons (6-6 bonds) and the driving force is relief of steric strain.
The reaction is of importance in the field of chemistry because it allows the introduction of useful extensions to the fullerene sphere. These extensions alter their properties, for instance solubility and electrochemical behavior, and therefore widen the range of potential technical applications.
The Bingelreaction in fullerene chemistry is a fullerene cyclopropanation reaction to a methanofullerene first discovered by C. Bingel in 1993 with the...
a reversible inter-cage C–C bond is formed: Cyclopropanation (the Bingelreaction) is another common method for functionalizing C60. Cyclopropanation...
old named reaction is the Claisen rearrangement (1912) and a recent named reaction is the Bingelreaction (1993). When the named reaction is difficult...
nucleophilic reaction is the Bingelreaction. Fullerene reacts with chlorobenzene and aluminium chloride in a Friedel-Crafts alkylation type reaction. In this...
Kulinkovich reaction form cyclopropanols via a reaction between esters and Grignard reagents in presence of a titanium alkoxide. The Bingelreaction is a specialised...
results. Fullerene is an unusual reactant in many organic reactions such as the Bingelreaction discovered in 1993. Researchers have been able to increase...
stacking. Just as in other fullerene reactions like the Bingelreaction or Diels-Alder reactions this reaction can be reversed. A thermal cycloelimination...
in fullerenes weakens their double-bonds; addition thereto is the Bingelreaction. Bonds adjacent to an electron-withdrawing substituent (e.g. a carbonyl...
Dictionary on Perseus Project. Kennedy 1961. Benedetti et al. 2007. Miller 2003. Bingel et al. 2011. Bishop, Felicity L.; Aizlewood, Lizzi; Adams, Alison E. M....
Labhart (Zürich), and 0.E. Polansky (Vienna) – to which at a later time W.A. Bingel (Göttingen), E. Ruch (Berlin), G. Wagniere (Zürich), and P. Schuster (Vienna)...
September 2017. Retrieved 25 September 2017. Farnsworth NR, Akerele O, Bingel AS, Soejarto DD, Guo Z (1985). "Medicinal plants in therapy". Bulletin of...
PMID 29603164. S2CID 4492779. Bingel AS, Benoit PS (February 1973). "Oral contraceptives: therapeutics versus adverse reactions, with an outlook for the future...
ISBN 978-0-471-26694-5. Bingel AS, Benoit PS (February 1973). "Oral contraceptives: therapeutics versus adverse reactions, with an outlook for the future...
1016/0002-9378(76)90804-8. PMID 952300. Bingel AS, Benoit PS (February 1973). "Oral contraceptives: therapeutics versus adverse reactions, with an outlook for the future...
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