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Atomic absorption spectroscopy information


Flame atomic absorption spectroscopy instrument
A scientist preparing solutions for atomic absorption spectroscopy, reflected in the glass window of the AAS's flame atomizer cover door

Atomic absorption spectroscopy (AAS) and atomic emission spectroscopy (AES) is a spectroanalytical procedure for the quantitative determination of chemical elements by free atoms in the gaseous state. Atomic absorption spectroscopy is based on absorption of light by free metallic ions.

In analytical chemistry the technique is used for determining the concentration of a particular element (the analyte) in a sample to be analyzed. AAS can be used to determine over 70 different elements in solution, or directly in solid samples via electrothermal vaporization,[1] and is used in pharmacology, biophysics, archaeology and toxicology research.

Atomic emission spectroscopy (AAS) was first used as an analytical technique, and the underlying principles were established in the second half of the 19th century by Robert Wilhelm Bunsen and Gustav Robert Kirchhoff, both professors at the University of Heidelberg, Germany.[2]

The modern form of AAS was largely developed during the 1950s by a team of Australian chemists. They were led by Sir Alan Walsh at the Commonwealth Scientific and Industrial Research Organisation (CSIRO), Division of Chemical Physics, in Melbourne, Australia.[3][4]

Atomic absorption spectrometry has many uses in different areas of chemistry such as clinical analysis of metals in biological fluids and tissues such as whole blood, plasma, urine, saliva, brain tissue, liver, hair, muscle tissue. Atomic absorption spectrometry can be used in qualitative and quantitative analysis.

  1. ^ "TAS-990 Atomic Absorption Spectrophotometer-纳米材料工程研究中心". ercn.henu.edu.cn. Retrieved 2022-10-12.
  2. ^ "Robert Bunsen and Gustav Kirchhoff". Science History Institute. Retrieved 20 March 2018.
  3. ^ McCarthy, G.J. "Walsh, Alan - Biographical entry". Encyclopedia of Australian Science. Retrieved 22 May 2012.
  4. ^ Koirtyohann, S. R. (1991). "A History of Atomic Absorption Spectrometry". Analytical Chemistry. 63 (21): 1024A–1031A. doi:10.1021/ac00021a716. ISSN 0003-2700.

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