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Adiabatic electron transfer information


Adiabatic electron-transfer is a type of oxidation-reduction processes. The mechanism is ubiquitous in nature in both the inorganic and biological spheres. Adiabatic electron-transfers proceed without making or breaking chemical bonds. Adiabatic electron-transfer can occur by either optical or thermal mechanisms.[1] [2] Electron transfer during a collision between an oxidant and a reductant occurs adiabatically on a continuous potential-energy surface.

  1. ^ Piechota, Eric J.; Meyer, Gerald J. (2019). "Introduction to Electron Transfer: Theoretical Foundations and Pedagogical Examples". Journal of Chemical Education. 96 (11): 2450–2466. Bibcode:2019JChEd..96.2450P. doi:10.1021/acs.jchemed.9b00489. S2CID 208754569.
  2. ^ Hush, N. S. (1967). Intervalence-transfer absorption. II. Theoretical considerations and spectroscopic data. Progress in Inorganic Chemistry. Vol. 8. pp. 391–444. doi:10.1002/9780470166093.ch7. ISBN 9780470166093.

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Adiabatic electron transfer

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