Adiabatic electron-transfer is a type of oxidation-reduction processes. The mechanism is ubiquitous in nature in both the inorganic and biological spheres. Adiabatic electron-transfers proceed without making or breaking chemical bonds. Adiabatic electron-transfer can occur by either optical or thermal mechanisms.[1][2] Electron transfer during a collision between an oxidant and a reductant occurs adiabatically on a continuous potential-energy surface.
^Piechota, Eric J.; Meyer, Gerald J. (2019). "Introduction to Electron Transfer: Theoretical Foundations and Pedagogical Examples". Journal of Chemical Education. 96 (11): 2450–2466. Bibcode:2019JChEd..96.2450P. doi:10.1021/acs.jchemed.9b00489. S2CID 208754569.
^Hush, N. S. (1967). Intervalence-transfer absorption. II. Theoretical considerations and spectroscopic data. Progress in Inorganic Chemistry. Vol. 8. pp. 391–444. doi:10.1002/9780470166093.ch7. ISBN 9780470166093.
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Adiabaticelectron-transfer is a type of oxidation-reduction processes. The mechanism is ubiquitous in nature in both the inorganic and biological spheres...
Retrieved 18 September 2015. Hush, N. S. (1961). "Adiabatic theory of outer sphere electron-transfer reactions in solution". Transactions of the Faraday...
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absorption, formation of excited electronic states, transfer of excitation energy, and the transfer of electrons and protons (hydrogen ions) in chemical processes...
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exist including electron cyclotron resonance heating (ECRH) and ion cyclotron resonance heating. This energy is usually transferred by microwaves. Plasma...
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Hush, Australian chemist known for his discovery of the role of adiabaticelectrontransfer between molecules in the process of oxidation; in Sydney (d....
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accurately calculated thermochemical data, although in the case of the "adiabatic connection functionals" the weights can be set a priori. For example,...
the work function (also called the electron affinity) between the two materials. This can lead to charge transfer as, for instance, analyzed by Harper...
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together. Contrast cohesion. adiabatic cooling adiabatic heating adiabatic process A process which occurs without transfer of heat or mass of substances...