Zambia competed at the 2012 Summer Olympics in London, held from 27 July to 12 August 2012. The country's participation at London marked its twelfth appearance in the Summer Olympics since its début at the 1964 Summer Olympics. The delegation consisted of seven competitors; three track and field athletes Gerald Phiri, Prince Mumba and Chauzje Choosha, one each in Boxing and Judo (Gilbert Choombe and Boas Munyonga) and two swimmers, Zane Jordan and Jade Ashleigh Howard. Phiri, Mumba, Choombe and Munyonga had qualified by meeting the standards in their respective sports, and Choosha, Jordan and Howard qualified by wildcard places. Mumba was the national flag bearer at the opening and closing ceremonies.
Phiri received a bye in the men's 100 metres and was eliminated at the first round stage and recorded his best time of the 2012 athletic season. Mumba and Choosha were both eliminated from the competition in the parliamentary heats, and Choombe was defeated by Australian Jeff Horn in Boxing's round of 32. Munyonga was disqualified in his round of 32 match against Takahiro Nakai by holding his opponent's leg, a move he later regretted. Jordan failed to advance beyond the heats of the men's 100 metre backstroke despite recording a new personal best, while his female counterpart Howard was also eliminated in the same stage in the women's 100 metre freestyle.
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