Trimesitylvanadium information

Trimesitylvanadium
Names
	IUPAC name 1,3,5-trimethylbenzene-6-ide;vanadium
	Other names Tris(2,4,6-trimethylphenyl)vanadium;
Identifiers
3D model (JSmol)	Interactive image;
ChemSpider	73949723;
PubChem CID	13202584;
	InChI InChI=1S/3C9H11.V/c31-7-4-8(2)6-9(3)5-7;/h34-5H,1-3H3; Key: WZDKKKNMPLHVJQ;
	SMILES CC1=CC(C)=C(C(C)=C1)[V](C1C(C)=CC(C)=CC=1C)C1C(C)=CC(C)=CC=1C;
Properties
Chemical formula	C27H33V
Molar mass	408.503 g·mol−1
Appearance	blue solid
	Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). Infobox references

Trimesitylvanadium (mesityl or Mes = 2,4,6-trimethylphenyl) is one of the organovanadium complexes with vanadium in an oxidation state of 3. This compound was first synthesized by W. Seidel and G. Kreisel in 1974.^[1]^[2] To prepare this compound, VCl₃(THF)₃ (THF = tetrahydrofuran) was reacted with Grignard reagent MesMgBr to form a blue solution at room temperature.^[3]^[4] It is precipitated by the addition of dioxane, which results in a blue solid. It is thermally stable, but it is also an air-sensitive compound.

^ Seidel, Wolfgang; Kreisel, Günter (January 1974). "Zur Darstellung von Trimesitylvanadin". Zeitschrift für Chemie. 14 (1): 25. doi:10.1002/zfch.19740140116. ISSN 0044-2402.
^ Seidel, W.; Kreisel, G. (November 1977). "Arylvanadin(III)-Verbindungen, III. Darstellung und Eigenschaften von Triarylvanadin-Verbindungen". Zeitschrift für anorganische und allgemeine Chemie. 435 (1): 146–152. doi:10.1002/zaac.19774350119. ISSN 0044-2313.
^ Vivanco, Marilin; Ruiz, Javier; Floriani, Carlo; Chiesi-Villa, Angiola; Rizzoli, Corrado (May 1993). "Chemistry of the vanadium-carbon .sigma. bond. 1. Insertion of carbon monoxide, isocyanides, carbon dioxide, and heterocumulenes into the V-C bond of tris(mesityl)vanadium(III)". Organometallics. 12 (5): 1794–1801. doi:10.1021/om00029a041. ISSN 0276-7333.
^ Gambarotta, Sandro; Floriani, Carlo; Chiesi-Villa, Angiola; Guastini, Carlo (1984). "A tri-σ-aryl vanadium(<scp>III</scp>) derivative: structural determination of trimesitylvanadium(<scp>III</scp>)–tetrahydrofuran". J. Chem. Soc., Chem. Commun. (13): 886–887. doi:10.1039/c39840000886. ISSN 0022-4936.

[1] Seidel, Wolfgang; Kreisel, Günter (January 1974). "Zur Darstellung von Trimesitylvanadin". Zeitschrift für Chemie. 14 (1): 25. doi:10.1002/zfch.19740140116. ISSN 0044-2402.

[:0-2] Seidel, W.; Kreisel, G. (November 1977). "Arylvanadin(III)-Verbindungen, III. Darstellung und Eigenschaften von Triarylvanadin-Verbindungen". Zeitschrift für anorganische und allgemeine Chemie. 435 (1): 146–152. doi:10.1002/zaac.19774350119. ISSN 0044-2313.

[:2-3] Vivanco, Marilin; Ruiz, Javier; Floriani, Carlo; Chiesi-Villa, Angiola; Rizzoli, Corrado (May 1993). "Chemistry of the vanadium-carbon .sigma. bond. 1. Insertion of carbon monoxide, isocyanides, carbon dioxide, and heterocumulenes into the V-C bond of tris(mesityl)vanadium(III)". Organometallics. 12 (5): 1794–1801. doi:10.1021/om00029a041. ISSN 0276-7333.

[:1-4] Gambarotta, Sandro; Floriani, Carlo; Chiesi-Villa, Angiola; Guastini, Carlo (1984). "A tri-σ-aryl vanadium(<scp>III</scp>) derivative: structural determination of trimesitylvanadium(<scp>III</scp>)–tetrahydrofuran". J. Chem. Soc., Chem. Commun. (13): 886–887. doi:10.1039/c39840000886. ISSN 0022-4936.

Trimesitylvanadium information

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