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Triglycine sulfate information


Triglycine sulfate
Names
IUPAC name
Glycine sulfate (3:1)
Other names
Glycine sulfate; TGS
Identifiers
CAS Number
  • 513-29-1 checkY
3D model (JSmol)
  • Interactive image
ChemSpider
  • 10111
ECHA InfoCard 100.007.414 Edit this at Wikidata
EC Number
  • 208-154-2
PubChem CID
  • 10551
UNII
  • NEQ4Q0R0YA checkY
CompTox Dashboard (EPA)
  • DTXSID40883415 Edit this at Wikidata
InChI
  • InChI=1S/3C2H5NO2.H2O4S/c3*3-1-2(4)5;1-5(2,3)4/h3*1,3H2,(H,4,5);(H2,1,2,3,4)
SMILES
  • O=C(O)CN.O=S(=O)(O)O.O=C(O)CN.O=C(O)CN
Properties
Chemical formula
C6H17N3O10S
Molar mass 323.27 g·mol−1
Appearance White powder
Density 1.69 g/cm3[1]
Structure
Crystal structure
Monoclinic
Space group
P21[2]
Lattice constant
a = 0.9417 nm, b = 1.2643 nm, c = 0.5735 nm
α = 90°, β = 110°, γ = 90°
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references

Triglycine sulfate (TGS) is a chemical compound with a formula (NH2CH2COOH)3·H2SO4. The empirical formula of TGS does not represent the molecular structure, which contains protonated glycine moieties and sulfate ions. TGS with protons replaced by deuterium is called deuterated TGS or DTGS; alternatively, DTGS may refer to doped TGS. By doping the DTGS with the amino acid L-Alanine, the crystal properties are improved and the new material is called Deuterated L-Alanine doped Triglycine Sulfate (DLATGS or DLTGS). These crystals are pyroelectric and ferroelectric which allows their use as photodetector elements in infrared spectroscopy and night vision applications.[3] TGS detectors have also been used as the target in vidicon cathode ray imager tubes.

TGS has a critical point for the order parameter of polarization, at 322.5 K.[4]

  1. ^ Kwan-Chi Kao (2004). Dielectric phenomena in solids: with emphasis on physical concepts of electronic processes. Academic Press. pp. 318–. ISBN 978-0-12-396561-5. Retrieved 12 May 2011.
  2. ^ Cite error: The named reference j1 was invoked but never defined (see the help page).
  3. ^ "Pyroelectric Detectors: Materials, Applications, and Working Principle" (PDF).
  4. ^ Gonzalo, J. A. (1966-04-15). "Critical Behavior of Ferroelectric Triglycine Sulfate". Physical Review. 144 (2): 662–665. Bibcode:1966PhRv..144..662G. doi:10.1103/PhysRev.144.662.

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