Thallide information

Thallides are compounds containing anions composed of thallium. There are several thallium atoms in a cluster, and it does not occur as a single Tl⁻ in thallides.^[1]^[2] They are a subclass of trielides,^[2] which also includes gallides and indides.^[3] A more general classification is polar intermetallics, as clusters contain delocalized multicentre bonds.^[4] Thallides were discovered by Eduard Zintl in 1932.^[5]

Mixed anion compounds with thallides include halides (bromides and chlorides),^[6] oxides,^[7] and tetrelates (silicate, germanate).^[8]

^ Thayer, John S. (2010). "Relativistic Effects and the Chemistry of the Heavier Main Group Elements". Relativistic Methods for Chemists. Challenges and Advances in Computational Chemistry and Physics. Vol. 10. Springer Netherlands. p. 73. doi:10.1007/978-1-4020-9975-5_2. ISBN 978-1-4020-9975-5.
^ ^a ^b Schwinghammer, Vanessa F.; Gärtner, Stefanie (28 February 2024). "[Tl 7 ] 7– Clusters in Mixed Alkali Metal Thallides Cs 7.29 K 5.71 Tl 13 and Cs 3.45 K 3.55 Tl 7". Inorganic Chemistry. doi:10.1021/acs.inorgchem.3c04034. PMID 38416695.
^ Lehmann, Bernard; Röhr, Caroline (2022-12-13). "Endohedral Ten-Vertex Clusters [Ga@Tl 10 ] 8− in the Mixed Trielides A 8 GaTl 10 ( A =K, Rb, Cs)". Zeitschrift für anorganische und allgemeine Chemie. 648 (23). doi:10.1002/zaac.202200204. ISSN 0044-2313.
^ Li, DongXu; Luo, GengGeng; Xiao, ZiJing; Dai, JingCao (January 2012). "Synthesis, structure and bonding of the hypoelectronic cluster compound Sr3Tl5". Science China Chemistry. 55 (1): 131–137. doi:10.1007/s11426-011-4382-z. ISSN 1674-7291.
^ Gärtner, Stefanie (2020-11-07). "Spotlight on Alkali Metals: The Structural Chemistry of Alkali Metal Thallides". Crystals. 10 (11): 1013. doi:10.3390/cryst10111013. ISSN 2073-4352.
^ Cite error: The named reference :5 was invoked but never defined (see the help page).
^ Karpov, Andrey; Jansen, Martin (2006). "A10Tl6O2(A = K, Rb) cluster compounds combining structural features of thallium cluster anions and of alkali metal sub-oxides". Chemical Communications (16): 1706–1708. doi:10.1039/b601802e. ISSN 1359-7345. PMID 16609778.
^ Saltykov, Vyacheslav; Nuss, Jürgen; Jansen, Martin (July 2011). "Cs 10 Tl 6 SiO 4 , Cs 10 Tl 6 GeO 4 , and Cs 10 Tl 6 SnO 3 – First Oxotetrelate Thallides, Double Salts Containing "Hypoelectronic" [Tl 6 ] 6– Clusters". Zeitschrift für anorganische und allgemeine Chemie. 637 (9): 1163–1168. doi:10.1002/zaac.201000358. ISSN 0044-2313.

[1] Thayer, John S. (2010). "Relativistic Effects and the Chemistry of the Heavier Main Group Elements". Relativistic Methods for Chemists. Challenges and Advances in Computational Chemistry and Physics. Vol. 10. Springer Netherlands. p. 73. doi:10.1007/978-1-4020-9975-5_2. ISBN 978-1-4020-9975-5.

[:0-2] Schwinghammer, Vanessa F.; Gärtner, Stefanie (28 February 2024). "[Tl 7 ] 7– Clusters in Mixed Alkali Metal Thallides Cs 7.29 K 5.71 Tl 13 and Cs 3.45 K 3.55 Tl 7". Inorganic Chemistry. doi:10.1021/acs.inorgchem.3c04034. PMID 38416695.

[:3-3] Lehmann, Bernard; Röhr, Caroline (2022-12-13). "Endohedral Ten-Vertex Clusters [Ga@Tl 10 ] 8− in the Mixed Trielides A 8 GaTl 10 ( A =K, Rb, Cs)". Zeitschrift für anorganische und allgemeine Chemie. 648 (23). doi:10.1002/zaac.202200204. ISSN 0044-2313.

[:18-4] Li, DongXu; Luo, GengGeng; Xiao, ZiJing; Dai, JingCao (January 2012). "Synthesis, structure and bonding of the hypoelectronic cluster compound Sr3Tl5". Science China Chemistry. 55 (1): 131–137. doi:10.1007/s11426-011-4382-z. ISSN 1674-7291.

[:1-5] Gärtner, Stefanie (2020-11-07). "Spotlight on Alkali Metals: The Structural Chemistry of Alkali Metal Thallides". Crystals. 10 (11): 1013. doi:10.3390/cryst10111013. ISSN 2073-4352.

[:5-6] Cite error: The named reference :5 was invoked but never defined (see the help page).

[:10-7] Karpov, Andrey; Jansen, Martin (2006). "A10Tl6O2(A = K, Rb) cluster compounds combining structural features of thallium cluster anions and of alkali metal sub-oxides". Chemical Communications (16): 1706–1708. doi:10.1039/b601802e. ISSN 1359-7345. PMID 16609778.

[:9-8] Saltykov, Vyacheslav; Nuss, Jürgen; Jansen, Martin (July 2011). "Cs 10 Tl 6 SiO 4 , Cs 10 Tl 6 GeO 4 , and Cs 10 Tl 6 SnO 3 – First Oxotetrelate Thallides, Double Salts Containing "Hypoelectronic" [Tl 6 ] 6– Clusters". Zeitschrift für anorganische und allgemeine Chemie. 637 (9): 1163–1168. doi:10.1002/zaac.201000358. ISSN 0044-2313.

Thallide information

and 13 Related for: Thallide information

Thallide

Thallium

Oxidation state

Thallium trifluoride

Thallane

Cyclopentadienylthallium

Thallium barium calcium copper oxide

Thallium triiodide

Thallous acetate

Thallium halides

Thallium azide

Group 13 hydride

Thallous malonate