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Tetrapropylammonium perruthenate information


Tetrapropylammonium perruthenate
Names
IUPAC name
Tetrapropylammonium perruthenate
Identifiers
CAS Number
  • 114615-82-6 checkY
3D model (JSmol)
  • Interactive image
Abbreviations TPAP
TPAPR
ChemSpider
  • 21170134 checkY
ECHA InfoCard 100.156.687 Edit this at Wikidata
PubChem CID
  • 127020979 incorrect structure
UNII
  • Y4N78L8V1T checkY
CompTox Dashboard (EPA)
  • DTXSID20894180 Edit this at Wikidata
InChI
  • InChI=1S/C12H28N.4O.Ru/c1-5-9-13(10-6-2,11-7-3)12-8-4;;;;;/h5-12H2,1-4H3;;;;;/q+1;;;;-1; ☒N
    Key: NQSIKKSFBQCBSI-UHFFFAOYSA-N ☒N
  • InChI=1/C12H28N.4O.Ru/c1-5-9-13(10-6-2,11-7-3)12-8-4;;;;;/h5-12H2,1-4H3;;;;;/q+1;;;;-1;/rC12H28N.O4Ru/c1-5-9-13(10-6-2,11-7-3)12-8-4;1-5(2,3)4/h5-12H2,1-4H3;/q+1;-1
    Key: NQSIKKSFBQCBSI-DQAXOFGLAB
SMILES
  • CCC[N+](CCC)(CCC)CCC.O=[Ru](=O)([O-])=O
Properties
Chemical formula
 C12H28NRuO4
Molar mass 351.43 g/mol
Appearance Green solid
Melting point 160 °C (320 °F; 433 K) (decomposition)
Hazards
GHS labelling:
Pictograms
 GHS03: OxidizingGHS07: Exclamation mark
Signal word
 Warning
Hazard statements
 H272, H315, H319, H335
Precautionary statements
 P210, P220, P221, P261, P264, P271, P280, P302+P352, P304+P340, P305+P351+P338, P312, P321, P332+P313, P337+P313, P362, P370+P378, P403+P233, P405, P501
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references

Tetrapropylammonium perruthenate (TPAP or TPAPR) is the chemical compound described by the formula N(C3H7)4RuO4. Sometimes known as the Ley–Griffith reagent, this ruthenium compound is used as a reagent in organic synthesis. This salt consists of the tetrapropylammonium cation and the perruthenate anion, RuO−4.

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Tetrapropylammonium perruthenate

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Tetrapropylammonium perruthenate (TPAP or TPAPR) is the chemical compound described by the formula N(C3H7)4RuO4. Sometimes known as the Ley–Griffith reagent...

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Tetrapropylammonium

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After synthesis, TPA is removed by thermolysis. The TPA salt tetrapropylammonium perruthenate (TPAP) is an effective and highly selective oxidiser, with...

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List of organic salts

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chloride Copper ibuprofenate Homatropine methylbromide Mellite Tetrapropylammonium perruthenate Collidinium p-toluenesulfonate Pyridinium chloride Tetrasodium...

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Nicolaou Taxol total synthesis

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acetonide, was selectively oxidized to the aldehyde using tetrapropylammonium perruthenate (TPAP) and N-methylmorpholine N-oxide. Aldehyde 2.6 served...

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TPAP

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TPAP can mean any of the following: Tetrapropylammonium perruthenate Trivial Pursuit: America Plays To Pimp A Butterfly (Kendrick Lamar album) This disambiguation...

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Alcohol oxidation

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Ley oxidation uses NMO as the stoichiometric oxidant with tetrapropylammonium perruthenate as a catalyst. Fétizon oxidation, also a seldom-used method...

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Holton Taxol total synthesis

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unprotected secondary alcohol was oxidized to ketone 43 using tetrapropylammonium perruthenate (TPAP) and N-methylmorpholine N-oxide (NMO). This ketone was...

Word Count : 1478
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