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Tetramethylethylene information


Tetramethylethylene
Names
Preferred IUPAC name
2,3-Dimethylbut-2-ene
Identifiers
CAS Number
  • 563-79-1
3D model (JSmol)
  • Interactive image
ChemSpider
  • 10776
ECHA InfoCard 100.008.422 Edit this at Wikidata
EC Number
  • 209-263-8
PubChem CID
  • 11250
UNII
  • 7UQ4B3F5JC checkY
CompTox Dashboard (EPA)
  • DTXSID2060339 Edit this at Wikidata
InChI
  • InChI=1S/C6H12/c1-5(2)6(3)4/h1-4H3
    Key: WGLLSSPDPJPLOR-UHFFFAOYSA-N
SMILES
  • CC(=C(C)C)C
Properties
Chemical formula
C6H12
Molar mass 84.162 g·mol−1
Appearance colorless liquid
Density 0.7075 g/cm3 (20 °C)
Melting point −74.6 °C (−102.3 °F; 198.6 K)
Boiling point 73.3 °C (163.9 °F; 346.4 K)
Critical point (T, P) 521.0(9) K, 3.4(1) MPa[1]
Solubility in water
insoluble
Solubility soluble in ethanol, ether, acetone, chloroform[1]
Magnetic susceptibility (χ)
−65.9×10−6 cm3·mol−1[1]
Refractive index (nD)
1.4122 (20 °C)[1]
Thermochemistry[1]
Heat capacity (C)
174.7 J·mol−1·K−1
Std molar
entropy (S298)
270.2 J·mol−1·K−1
Std enthalpy of
formation fH298)
−101.4 kJ·mol−1 (liquid)
−68.1 kJ·mol−1 (gas)
Enthalpy of fusion fHfus)
6.45 kJ·mol−1 (at melting point)
Enthalpy of vaporization fHvap)
32.51 kJ·mol−1 (25 °C)
29.64 kJ·mol−1 (at boiling point)
Hazards
GHS labelling:
Pictograms
GHS02: FlammableGHS08: Health hazard
Signal word
Danger
Hazard statements
H225, H304
Precautionary statements
P210, P233, P240, P241, P242, P243, P280, P301+P310, P303+P361+P353, P331, P370+P378, P403+P235, P405, P501
Flash point −8 °C
Autoignition
temperature
401 °C[1]
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references

Tetramethylethylene is a hydrocarbon with the formula Me2C=CMe2 (Me = methyl). A colorless liquid, it is the simplest tetrasubstituted alkene.

  1. ^ a b c d e f CRC handbook of chemistry and physics : a ready-reference book of chemical and physical data. William M. Haynes, David R. Lide, Thomas J. Bruno (2016-2017, 97th ed.). Boca Raton, Florida. 2016. ISBN 978-1-4987-5428-6. OCLC 930681942.{{cite book}}: CS1 maint: location missing publisher (link) CS1 maint: others (link)

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Tetramethylethylene

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Tetramethylethylene is a hydrocarbon with the formula Me2C=CMe2 (Me = methyl). A colorless liquid, it is the simplest tetrasubstituted alkene. It can...

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Pinacol

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3-diol Other names 2,3-Dimethyl-2,3-butanediol Tetramethylethylene glycol 1,1,2,2-Tetramethylethylene glycol Pinacone Identifiers CAS Number 76-09-5 Y...

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Disiamylborane

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2-trimethylpropyl)borane, ThxBH2), a primary borane obtained by hydroboration of tetramethylethylene. The prefix disiamyl is an abbreviation for "di-sec-isoamyl", where...

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Pinacol coupling reaction

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named after pinacol (also known as 2,3-dimethyl-2,3-butanediol or tetramethylethylene glycol), which is the product of this reaction when done with acetone...

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Thexylborane

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accessed monoalkylborane. It is produced by the hydroboration of tetramethylethylene: B2H6 + 2 Me2C=CMe2 → [Me2CHCMe2BH2]2 Thexylborane is generated in...

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Pinacol rearrangement

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Charles Friedel, believed the reaction product to be the epoxide tetramethylethylene oxide in analogy with reactions of ethylene glycol. Finally Butlerov...

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Halogen addition reaction

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XLVIII. Halonium ion formation via neighboring halogen participation. Tetramethylethylene halonium ions". Journal of the American Chemical Society. 89 (18):...

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Organolithium reagent

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Lewis bases such as tetrahydrofuran (THF), diethyl ether (Et2O), tetramethylethylene diamine (TMEDA) or hexamethylphosphoramide (HMPA). Methyllithium...

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Hydroboration

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example is thexylborane (ThxBH2), produced by the hydroboration of tetramethylethylene: B2H6 + 2 Me2C=CMe2 → [Me2CHCMe2BH2]2 A chiral example is monoisopinocampheylborane...

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