Global InformationSuperelectrophilic anion information
Superelectrophilic anions are a class of molecular ions that exhibit highly electrophilic reaction behavior despite their overall negative charge.[1][2] Thus, they are even able to bind the unreactive noble gases or molecular nitrogen at room temperature.[1][2][3] The only representatives known so far are the fragment ions of the type [B12X11]– derived from the closo-dodecaborate dianions [B12X12]2–. X represents a substituent connected to a boron atom (cf. Fig. 1). For this reason, the following article deals exclusively with superelectrophilic anions of this type.
- ^ a b Mayer, Martin; Lessen, Valentin van; Rohdenburg, Markus; Hou, Gao-Lei; Yang, Zheng; Exner, Rüdiger M.; Aprà, Edoardo; Azov, Vladimir A.; Grabowsky, Simon; Xantheas, Sotiris S.; Asmis, Knut R. (2019-04-23). "Rational design of an argon-binding superelectrophilic anion". Proceedings of the National Academy of Sciences. 116 (17): 8167–8172. doi:10.1073/pnas.1820812116. ISSN 0027-8424. PMC 6486711. PMID 30952786.
- ^ a b Rohdenburg, Markus; Mayer, Martin; Grellmann, Max; Jenne, Carsten; Borrmann, Tobias; Kleemiss, Florian; Azov, Vladimir A.; Asmis, Knut R.; Grabowsky, Simon; Warneke, Jonas (2017). "Superelectrophilic Behavior of an Anion Demonstrated by the Spontaneous Binding of Noble Gases to [B12Cl11]−". Angewandte Chemie International Edition. 56 (27): 7980–7985. doi:10.1002/anie.201702237. ISSN 1521-3773. PMID 28560843.
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