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Sodium trichloroacetate information


Sodium trichloroacetate
Names
Preferred IUPAC name
Sodium trichloroacetate
Identifiers
CAS Number
  • 650-51-1
3D model (JSmol)
  • Interactive image
ChemSpider
  • 12073
ECHA InfoCard 100.010.437 Edit this at Wikidata
EC Number
  • 211-479-2
PubChem CID
  • 23681045
RTECS number
  • AJ9100000
UNII
  • 2N76A3BRJ0
CompTox Dashboard (EPA)
  • DTXSID6034924 Edit this at Wikidata
InChI
  • Key: SAQSTQBVENFSKT-UHFFFAOYSA-M
  • InChI=1S/C2HCl3O2.Na/c3-2(4,5)1(6)7;/h(H,6,7);/q;+1/p-1
SMILES
  • C(C(=O)[O-])(Cl)(Cl)Cl.[Na+]
Properties
Chemical formula
C2Cl3NaO2
Molar mass 185.36 g/mol
Appearance White powder
Density ~1.5 g/mL−1
Melting point 200 °C (392 °F; 473 K)
Boiling point Decomposes
Solubility in water
55 g / 100 ml
Solubility Soluble in methanol and ethanol, slightly soluble in acetone, not soluble in ethers and hydrocarbons
Acidity (pKa) 0.7 (conjugate acid)
Hazards
Occupational safety and health (OHS/OSH):
Main hazards
Corrosive
GHS labelling:
Pictograms
GHS07: Exclamation markGHS09: Environmental hazard
Signal word
Warning
Hazard statements
H335, H410
Precautionary statements
P261, P271, P273, P304+P340, P312, P391, P403+P233, P405, P501
NFPA 704 (fire diamond)
NFPA 704 four-colored diamondHealth 3: Short exposure could cause serious temporary or residual injury. E.g. chlorine gasFlammability 1: Must be pre-heated before ignition can occur. Flash point over 93 °C (200 °F). E.g. canola oilInstability 1: Normally stable, but can become unstable at elevated temperatures and pressures. E.g. calciumSpecial hazards (white): no code
3
1
1
Flash point Non-flammable
Autoignition
temperature
Non-flammable
Related compounds
Other anions
Sodium trifluoroacetate
Other cations
Trichloroacetic acid
Related compounds
Sodium chloroacetate
Sodium acetate
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references

Sodium trichloroacetate is a chemical compound with a formula of CCl3CO2Na. It is used to increase sensitivity and precision during transcript mapping.[1] It was previously used as an herbicide starting in the 1950s but regulators removed it from the market in the late 1980s and early 1990s.[2][3][4][5]

  1. ^ Murray, M. G. (1986). "Use of sodium trichloroacetate and mung bean nuclease to increase sensitivity and precision during transcript mapping". Analytical Biochemistry. 158 (1): 165–170. doi:10.1016/0003-2697(86)90605-6. ISSN 0003-2697. PMID 2432801.
  2. ^ TCA-sodium in the Pesticide Properties DataBase (PPDB), accessed June 20, 2014
  3. ^ G. S. Rai and C. L. Hamner Persistence of Sodium Trichloroacetate in Different Soil Types Weeds 2(4) Oct. 1953: 271-279
  4. ^ OECD Trichloroacetic Acid CAS N°: 76-03-9 Archived 2016-03-04 at the Wayback Machine Accessed June 20, 2014
  5. ^ EPA December 1991. trichloroacetic acid (TCA) EPA Cancellation 12/91 Accessed June 20, 2014

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Sodium trichloroacetate

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Sodium trichloroacetate is a chemical compound with a formula of CCl3CO2Na. It is used to increase sensitivity and precision during transcript mapping...

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Trichloroacetic acid

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considered safe for use for this purpose during pregnancy. The sodium salt (sodium trichloroacetate) was used as an herbicide starting in the 1950s but regulators...

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Sodium trifluoroacetate

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Sodium trifluoroacetate is a chemical compound with a formula of CF3CO2Na. It is the sodium salt of trifluoroacetic acid. It is used as a source of...

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Organomercury chemistry

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presence of phenylmercuric chloride. A convenient carbene source is sodium trichloroacetate. This compound on heating releases dichlorocarbene: C6H5HgCCl3...

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Malayan Emergency

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jungle clearings. Helicopters and fixed-wing aircraft despatched sodium trichloroacetate and Trioxone, along with pellets of chlorophenyl N,N-dimethyl-1-naphthylamine...

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Fullerene chemistry

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methanofullerenes. The reaction of fullerene with dichlorocarbene (created by sodium trichloroacetate pyrolysis) was first reported in 1993. A single addition takes...

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Ronald Yeldham

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Malayan Emergency, in 1952, he was instrumental in the use of sodium trichloroacetate as a defoliant. Yeldham then held civil appointments in Kenya,...

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Dichlorocarbene

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+ H2O Another precursor to dichlorocarbene is ethyl trichloroacetate. Upon treatment with sodium methoxide it releases CCl2. Phenyl(trichloromethyl)mercury...

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Tetrachloroethylene

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tetrachlorobutadiene, dichlorocyclopentane, dichloropentene, methyl trichloroacetate, tetrachloroacetone, tetrachloropropene, trichlorocyclopentane, trichloropentene...

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List of UN numbers 2501 to 2600

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inhibited UN 2532 ? (UN No. no longer in use) UN 2533 6.1 Methyl trichloroacetate UN 2534 2 Methylchlorosilane UN 2535 3 4-Methylmorpholine or n-methylmorpholine...

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