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Ring expansion and contraction information


Ring expansion and ring contraction reactions expand or contract rings, usually in organic chemistry. The term usually refers to reactions involve making and breaking C-C bonds,[1] Diverse mechanisms lead to these kinds of reactions.

The bond migration step of the pinacol type rearrangement.
  1. ^ Cite error: The named reference :0 was invoked but never defined (see the help page).

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Ring expansion and contraction

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Ring expansion and ring contraction reactions expand or contract rings, usually in organic chemistry. The term usually refers to reactions involve making...

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Cyclic compound

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Examples include: ring opening metathesis, which can also be used to accomplish a specific type of polymerization. Ring expansion and contraction reactions are...

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Isomerase

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of a ring structure. This category is not broken down any further. All entries presently include: A classic example of ring opening and contraction is the...

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Expansion joint

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the movement of the subfloor and the tiles themselves due to thermal expansion and contraction, moisture variations, and structural shifts. These joints...

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Steroid

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side chain at C-17 and an hydroxyl group at C-3 In addition to the ring scissions (cleavages), expansions and contractions (cleavage and reclosing to a larger...

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Secosteroid

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skeleton derived therefrom by one or more bond scissions or ring expansions or contractions." Ayers D (1972). Bioscientific Terminology. Tucson: University...

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Washington Nationals

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failed contraction plan, the Expos were purchased by MLB, which sought to move the team to a new city. Washington, D.C., was chosen in 2004, and the Nationals...

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Big Crunch

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parameter, and cosmological constant. If the expansion stopped, then contraction will inevitably follow, accelerating as time passes and finishing the...

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1979 NHL expansion

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willing to keep the team in St. Louis and save them from contraction took over the team. In 1992, the NHL added an expansion franchise in Ottawa. The league...

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Interference fit

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an undersized hole, sometimes used in combination: force and thermal expansion or contraction. There are at least three different terms used to describe...

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Theory of relativity

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unified entity of space and time, relativity of simultaneity, kinematic and gravitational time dilation, and length contraction. In the field of physics...

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Mitral valve

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diastole with contraction of the left atrium, and the mitral valve closes during systole with contraction of the left ventricle. The valve opens and closes because...

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Tensor

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down and to the left on the table. Symmetrically, lowering an index corresponds to moving diagonally up and to the right on the table. Contraction of an...

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Piping and plumbing fitting

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different materials, including: expansion adapters which have a flexible section to absorb expansion or contraction from two dissimilar pipe materials...

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Long Depression

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cycles and depressions: an encyclopedia. New York: Garland Publishing. pp. 148–149. ISBN 0-8240-0944-4. "Business Cycle Expansions and Contractions". National...

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Cheung Chau Mini Great Wall

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expand and contract at variable rates during daytime and nighttime, different minerals may lose grains by repeated expansion and contraction. Grains...

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Ciliary muscle

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ciliary body and iris. Parasympathetic activation of the M3 muscarinic receptors causes ciliary muscle contraction. The effect of contraction is to decrease...

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Expanding monomer

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cyclopentene dimer leads to expansion of 5.21% and the conversion of adamantane even to expansion of 14.15%. The third effect is the ring-opening effect which...

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Nitrene

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rotation and thus producing a mixture of stereochemistry. Arylnitrene ring-expansion and ring-contraction: Aryl nitrenes show ring expansion to 7-membered...

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Nyctereutes

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influenced by environmental and climatic changes, such as the expansion and contraction of forests and the fluctuations of temperature and precipitation. They...

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Ehrenfest paradox

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the periphery experience the Lorentz contraction, but the rods upon the diameter do not experience this contraction (along their lengths!). It therefore...

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Major professional sports leagues in the United States and Canada

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the longevity and stability of the league, as measured by the year founded, the last time the league underwent expansion and contraction, the number of...

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Alcubierre drive

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a contraction of space ahead of the bubble and an expansion behind, but this interpretation could be misleading, since the contraction and expansion actually...

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Patterned ground

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freeze the soil before it thaws again in the morning. This daily expansion and contraction of the soil prevents the establishment of vegetation. Frost also...

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Friedmann equations

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error), the dark energy does not lead to contraction of the universe but rather may accelerate its expansion. An expression for the critical density is...

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Tensor product

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{\displaystyle \{u_{i}\}} and its dual basis { u i ∗ } {\displaystyle \{u_{i}^{*}\}} as in the section "Evaluation map and tensor contraction" above: { H o m (...

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Major League Baseball

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in favor of contraction. Several MLB teams had been considered for elimination in early talks about contraction, but the Montreal Expos and the Minnesota...

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Montreal Expos

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political leaders in Montreal sought an MLB franchise, and when the National League evaluated expansion candidates for the 1969 season, it awarded a team to...

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