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Relations between heat capacities information


In thermodynamics, the heat capacity at constant volume, , and the heat capacity at constant pressure, , are extensive properties that have the magnitude of energy divided by temperature.

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Relations between heat capacities

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temperature. The laws of thermodynamics imply the following relations between these two heat capacities (Gaskell 2003:23): C P − C V = V T α 2 β T {\displaystyle...

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Heat capacity ratio

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Relations between heat capacities Heat capacity Specific heat capacity Speed of sound Thermodynamic equations Thermodynamics Volumetric heat capacity...

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Specific heat capacity

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=c_{p}/c_{V}} is the heat capacity ratio. The term specific heat may also refer to the ratio between the specific heat capacities of a substance at a given...

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Heat capacity

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the effective heat capacity of the gas, in that situation, will have a value intermediate between its isobaric and isochoric capacities C p {\displaystyle...

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Entropy

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of the system. Important examples are the Maxwell relations and the relations between heat capacities. Thermodynamic entropy is central in chemical thermodynamics...

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Heat

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In thermodynamics, heat is the thermal energy transferred between systems due to a temperature difference. In colloquial use, heat sometimes refers to...

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Onsager reciprocal relations

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In thermodynamics, the Onsager reciprocal relations express the equality of certain ratios between flows and forces in thermodynamic systems out of equilibrium...

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Debye model

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phonon contribution to the specific heat (heat capacity) in a solid. It treats the vibrations of the atomic lattice (heat) as phonons in a box in contrast...

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Intensive and extensive properties

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thermodynamic relations. A specific property is the intensive property obtained by dividing an extensive property of a system by its mass. For example, heat capacity...

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Isobaric process

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mol−1 deg−1. The ratio γ {\displaystyle \gamma } of the two heat capacities is 1.4. The heat Q required to bring the gas from 300 to 600 K is Q = Δ H =...

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Polytropic process

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{\displaystyle \gamma } is the ratio of the heat capacity at constant pressure ( C P {\displaystyle C_{P}} ) to heat capacity at constant volume ( C V {\displaystyle...

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Thermal conductivity and resistivity

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conduct heat. It is commonly denoted by k {\displaystyle k} , λ {\displaystyle \lambda } , or κ {\displaystyle \kappa } and is measured in W·m−1·K−1. Heat transfer...

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Zeroth law of thermodynamics

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linked by a wall permeable only to heat, and they do not change over time. Another formulation by Maxwell is "All heat is of the same kind". Another statement...

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Latent heat

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transferred as heat, with a resultant temperature change in a body. The terms sensible heat and latent heat refer to energy transferred between a body and...

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Laws of thermodynamics

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thermodynamic processes, such as thermodynamic work and heat, and establish relationships between them. They state empirical facts that form a basis of...

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Temperature

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and the observed heat capacity of monatomic (or 'noble') gases. The ideal gas law is based on observed empirical relationships between pressure (p), volume...

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Ideal gas

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approximation). Since the heat capacity depends on the atomic or molecular nature of the gas, macroscopic measurements on heat capacity provide useful information...

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Thermodynamic equations

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difference between the specific heat capacities is the same as the universal gas constant. This relation is represented by the difference between Cp and Cv:...

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Heat engine

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can be any system with a non-zero heat capacity, but it usually is a gas or liquid. During this process, some heat is normally lost to the surroundings...

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Carnot cycle

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In a Carnot cycle, a system or engine transfers energy in the form of heat between two thermal reservoirs at temperatures T H {\displaystyle T_{H}} and...

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Thermoelectric effect

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different temperature on each side. Conversely, when a voltage is applied to it, heat is transferred from one side to the other, creating a temperature difference...

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Thermal efficiency

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a heat pump is more than 1. These values are further restricted by the Carnot theorem. In general, energy conversion efficiency is the ratio between the...

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Second law of thermodynamics

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that are bound by their own gravity, such as stars, can have negative heat capacities. As they contract, both their total energy and their entropy decrease...

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Heat transfer physics

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Heat transfer physics describes the kinetics of energy storage, transport, and energy transformation by principal energy carriers: phonons (lattice vibration...

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Maxwell relations

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Maxwell's relations are a set of equations in thermodynamics which are derivable from the symmetry of second derivatives and from the definitions of the...

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Effects of climate change on livestock

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time, the already observed warming between 1981 and 2017 would have increased relative annual heat stress by between 0.9 and 6.4% per year. It is considered...

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