Equivalent circuit for an electrochemical reaction
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In electrochemistry, a Randles circuit is an equivalent electrical circuit that consists of an active electrolyte resistance RS in series with the parallel combination of the double-layer capacitance Cdl and an impedance (Zw) of a faradaic reaction. It is commonly used in electrochemical impedance spectroscopy (EIS) for interpretation of impedance spectra, often with a constant phase element (CPE) replacing the double layer capacity.
The Randles equivalent circuit is one of the simplest possible models describing processes at the electrochemical interface. In real electrochemical systems, impedance spectra are usually more complicated and, thus, the Randles circuit may not give appropriate results.
thus, the Randlescircuit may not give appropriate results. Figure 1 shows the equivalent circuit initially proposed by John Edward Brough Randles for modeling...
Randles is a surname which may refer to: Elizabeth Randles (1800–1829), Welsh child prodigy harpist and pianist Jan Randles, Australian Paralympic runner...
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In 1954, his career had stalled so he and Valerie Joy left the variety circuit and took a pub, the Raglan, in Hulme, just a short step from Hulme Hippodrome...
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games. Carter also competed on the International Triathlon Union World Cup circuit as a professional for many years, culminating in a silver medal in 2006...
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