Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references
Chemical compound
Potassium tetracarbonyliron hydride is the inorganic salt with the formula K[HFe(CO)4]. A pale yellow solid, it is the potassium salt of [HFe(CO)4]−, which is the conjugate base of iron tetracarbonyl dihydride:[1][2]
H2Fe(CO)4 + KOH → K[HFe(CO)4] + H2O
Potassium tetracarbonyliron hydride is prepared by treating iron pentacarbonyl with potassium hydroxide:[3]
Fe(CO)5 + 2 KOH → K[HFe(CO)4] + KHCO3
Potassium tetracarbonyliron hydride is an intermediate in the synthesis of trisubstituted phosphine complexes:[4]
^Brunet, Jean-Jacques (1998). "Coordination Chemistry of Mononuclear Iron Carbonyl Complexes". Coordination Chemistry Reviews. 178–180: 331–351. doi:10.1016/S0010-8545(98)00075-7.
^Brunet, J.J. (1990). "Tetracarbonylhydridoferrates, MHFe(CO)4: Versatile tools in Organic Synthesis and Catalysis". Chem. Rev.90 (6): 1041–1059. doi:10.1021/cr00104a006.
^Brunet, J.-J.; Kindela, F. B.; Neibecker, D. (1992). "Trans-Tricarbonylbis(Phosphine)Iron(0) Complexes: One-Pot Syntheses from Pentacarbonyliron". trans-Tricarbonylbis(Phosphine)Iron(0) Complexes: One-Pot Syntheses from Pentacarbonyliron. Inorganic Syntheses. Vol. 29. pp. 151–156. doi:10.1002/9780470132609.ch36. ISBN 9780470132609.
^Brunet, J.-J.; Kindela, F. B.; Neibecker (1996). "One-Pot Synthesis of Dicarbonyltris(Phosphane)Iron(0) Complexes from Pentacarbonyliron". Inorganic Syntheses. Inorganic Syntheses. Vol. 31. pp. 202–210. doi:10.1002/9780470132623.ch30. ISBN 9780470132623.
and 3 Related for: Potassium tetracarbonyliron hydride information
Potassiumtetracarbonylironhydride is the inorganic salt with the formula K[HFe(CO)4]. A pale yellow solid, it is the potassium salt of [HFe(CO)4]−, which...
transfer from water to the iron hydride anion. HFe(CO)− 4 + H2O → H2Fe(CO)4 + OH− Potassiumtetracarbonylironhydride Collman's reagent Tsai, J.-C.; Khan...
solvent. Transition metal complexes cam be made by using lithium aluminium hydride to reduce a trichlorogermyl complex (−GeCl3), which in turn can be made...