Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Chemical compound
Phenylmagnesium bromide, with the simplified formula C 6H 5MgBr, is a magnesium-containing organometallic compound. It is commercially available as a solution in diethyl ether or tetrahydrofuran (THF). Phenylmagnesium bromide is a Grignard reagent. It is often used as a synthetic equivalent for the phenyl "Ph−" synthon.
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Phenylmagnesiumbromide, with the simplified formula C 6H 5MgBr, is a magnesium-containing organometallic compound. It is commercially available as a...
compounds. One method involves its conversion to the Grignard reagent, phenylmagnesiumbromide. This reagent can be used, e.g. in the reaction with carbon dioxide...
Two typical examples are methylmagnesium chloride Cl−Mg−CH3 and phenylmagnesiumbromide (C6H5)−Mg−Br. They are a subclass of the organomagnesium compounds...
toluene to benzoic acid. For laboratory use, Grignard reaction of phenylmagnesiumbromide (C6H5MgBr) with formaldehyde and the Cannizzaro reaction of benzaldehyde...
phenyllithium with zinc bromide: 2 PhLi + ZnBr2 → Ph2Zn + 2 LiBr It may also be prepared by the reaction of phenylmagnesiumbromide with zinc chloride or...
cation. Representative reagents include phenyllithium (C6H5Li) and phenylmagnesiumbromide (C6H5MgBr). Electrophiles are attacked by benzene to give phenyl...
include the transfer of air-sensitive or pyrophoric reagents such as phenylmagnesiumbromide and n-butyllithium respectively. Glass syringes are also used to...
example, benzophenone imine can also be synthesized by addition of phenylmagnesiumbromide to benzonitrile followed by careful hydrolysis (lest the imine...
converted to benzoic acid by "carboxylation" of the intermediate phenylmagnesiumbromide. This synthesis offers a convenient exercise for students to carry...
with haloalkanes. Examples of Grignard reagents are phenylmagnesiumbromide and ethylmagnesium bromide. The Grignard reagents function as a common nucleophile...
solvents. It is prepared by treatment of bismuth trichloride with phenylmagnesiumbromide. BiCl3 + 3 C6H5MgBr3 → Bi(C6H5)3 + 3 MgBrCl Structurally it resembles...
synthesize phenylboronic acid. One of the most common synthesis uses phenylmagnesiumbromide and trimethyl borate to form the ester PhB(OMe)2, which is then...
In the laboratory, biphenyl can also be synthesized by treating phenylmagnesiumbromide with copper(II) salts. It can also be prepared using diazonium...
Diphenylmethanol may be prepared by a Grignard reaction between phenylmagnesiumbromide and benzaldehyde[citation needed]. An alternative method involves...
Phenylsilane is produced in two steps from Si(OEt)4. In the first step, phenylmagnesiumbromide is added to form Ph−Si(OEt)3 via a Grignard reaction. Reduction...
known in organic chemistry is diphenyldiselenide, prepared from phenylmagnesiumbromide and selenium followed by oxidation of the product PhSeMgBr. Selanyl...
in the laboratory by treatment of phosphorus trichloride with phenylmagnesiumbromide or phenyllithium. The industrial synthesis involves the reaction...
a potential analgesic in 1947 by Ziering et al. by reaction of phenylmagnesiumbromide with 1-methyl-4-piperidinone. It was tested as a treatment for...
borate esters. For example, phenylboronic acid is produced from phenylmagnesiumbromide and trimethyl borate followed by hydrolysis PhMgBr + B(OMe)3 →...
Rieke magnesium. Examples of Grignard reagents are phenylmagnesiumbromide and ethylmagnesium bromide. These simplified formulas are deceptive: Grignard...
organic synthesis. Benzeneselenol is prepared by the reaction of phenylmagnesiumbromide and selenium: PhMgBr + Se → PhSeMgBr PhSeMgBr + HCl → PhSeH + MgBrCl...
tetrahydrofuran. Relative to the more commonly encountered methylmagnesium bromide and methylmagnesium iodide, methylmagnesium chloride offers the advantages...
point 121–123 °C) can be prepared by reaction of mercury chloride and phenylmagnesiumbromide. A related preparation entails formation of phenylsodium in the...
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