Phanephos information

Phanephos
Names
	IUPAC name (S)-(+)-4,12-Bis(diphenylphosphino)-[2.2]-paracyclophane; (R)-(−)-4,12-Bis(diphenylphosphino)-[2.2]-paracyclophane
	Other names (S)-Phanephos; (R)-Phanephos
Identifiers
CAS Number	(S): 364732-88-7 ; (R): 192463-40-4 ;
3D model (JSmol)	(S): Interactive image;
ChemSpider	(S): 9040059;
ECHA InfoCard	100.217.129
EC Number	(R): 690-034-8;
PubChem CID	(S): 10864772;
CompTox Dashboard (EPA)	(S): DTXSID301045593 ;
	InChI InChI=1S/C40H34P2/c1-5-13-35(14-6-1)41(36-15-7-2-8-16-36)39-29-31-21-25-33(39)27-23-32-22-26-34(28-24-31)40(30-32)42(37-17-9-3-10-18-37)38-19-11-4-12-20-38/h1-22,25-26,29-30H,23-24,27-28H2 Key: GYZZZILPVUYAFJ-UHFFFAOYSA-N; (S): InChI=1/C40H34P2/c1-5-13-35(14-6-1)41(36-15-7-2-8-16-36)39-29-31-21-25-33(39)27-23-32-22-26-34(28-24-31)40(30-32)42(37-17-9-3-10-18-37)38-19-11-4-12-20-38/h1-22,25-26,29-30H,23-24,27-28H2 Key: GYZZZILPVUYAFJ-UHFFFAOYAH;
	SMILES (S): C1CC2=C(C=C(CCC3=C(C=C1C=C3)P(C4=CC=CC=C4)C5=CC=CC=C5)C=C2)P(C6=CC=CC=C6)C7=CC=CC=C7;
Properties
Chemical formula	C40H34P2
Molar mass	576.660 g·mol−1
Appearance	White to off-white powder or crystals
Melting point	222 to 225 °C (432 to 437 °F; 495 to 498 K)
	Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). Infobox references

Phanephos is an organophosphorus compound with the chemical formula (C₂H₄)₂(C₆H₃PPh₂)₂ (Ph = C₆H₅). It is a white solid that is soluble in organic solvents. It is an example of a chiral C₂-symmetric diphosphine ligand used in asymmetric hydrogenation. Many substituents have been introduced in place of the phenyl groups, e.g., i-Pr, C₆H₁₁, etc and a variety of chiral diphosphine ligands have been reported in asymmetric catalysis since the 1960s.