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Peroxynitrate information


Peroxynitrate
Identifiers
3D model (JSmol)
  • Interactive image
ChEBI
  • CHEBI:29270
ChemSpider
  • 4574117
PubChem CID
  • 5460620
InChI
  • InChI=1S/HNO4/c2-1(3)5-4/h4H/p-1
    Key: UUZZMWZGAZGXSF-UHFFFAOYSA-M
SMILES
  • [N+](=O)([O-])O[O-]
Properties
Chemical formula
NO4
Molar mass 78.004 g·mol−1
Related compounds
Related compounds
peroxycarbonate; peroxysulfate
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references

Peroxynitrate (or peroxonitrate) refers to salts of the unstable peroxynitric acid, HNO4. Peroxynitrate is unstable and decomposes to nitrate and dioxygen.[1]

No solid peroxynitrate salts are known.[2] However, there is a report that the chemist Sebastian Moiseevich Tanatar produced sodium peroxynitrate octahydrate (NaNO3·H2O2·8H2O) by evaporating a solution of sodium nitrate and hydrogen peroxide until crystallisation begins and then mixing with alcohol to form crystals of the octahydrate.[3]

  1. ^ Miyamoto, Sayuri; Ronsein, Graziella E.; Corrêa, Thaís C.; Martinez, Glaucia R.; Medeiros, Marisa H. G.; Di Mascio, Paolo (2009). "Direct evidence of singlet molecular oxygen generation from peroxynitrate, a decomposition product of peroxynitrite". Dalton Transactions (29): 5720. doi:10.1039/b905560f. ISSN 1477-9226.
  2. ^ Greenwood, Norman N.; Earnshaw, Alan (1997). Chemistry of the Elements (2nd ed.). Butterworth-Heinemann. ISBN 978-0-08-037941-8.
  3. ^ Mellor, Joseph William (1922). A Comprehensive Treatise on Inorganic and Theoretical Chemistry, Volume 2. New York: Longmans, Green and Co. p. 816.

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Peroxynitrate

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Peroxynitrate (or peroxonitrate) refers to salts of the unstable peroxynitric acid, HNO4. Peroxynitrate is unstable and decomposes to nitrate and dioxygen...

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NO4

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Orthonitrate, a chemical ion composed of nitrogen and oxygen with a 3− charge Peroxynitrate, another chemical ion composed of nitrogen and oxygen with a 1− charge...

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Peroxynitric acid

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formula HNO 4. It is an oxyacid of nitrogen, after peroxynitrous acid. Peroxynitrate, the conjugate base of peroxynitric acid, is formed rapidly during decomposition...

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Chemical ionization

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Peroxynitrate chemical ionization mass spectrometer at the US National Oceanic and Atmospheric Administration...

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Nitrate

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anion NO− 2 Nitrogen oxide Nitrogen trioxide, the neutral radical NO 3 Peroxynitrate, OONO– 2 Sodium nitrate Laue W, Thiemann M, Scheibler E, Wiegand KW...

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Nitrogen oxide

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O=N−O− or NO−2 Nitrate O2N−O− or NO−3 Peroxynitrite O=N−O−O− or NO−3 Peroxynitrate O2N−O−O− or NO−4 Orthonitrate +N(−O−)4 or NO3−4 Hyponitrite −O−N=N−O−...

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Glossary of chemical formulae

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14797-65-0 NO2Cl nitryl chloride 13444-90-1 NO3− nitrate ion 14797-55-8 NO4- peroxynitrate ion N2 nitrogen 7727-37-9 N2H2 diazene 3618-05-1 N2H4 hydrazine 302-01-2...

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Oxyacid

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Nitrogen +5 HNO 3 Nitric acid NO− 3 Nitrate HNO 4 Peroxynitric acid NO− 4 Peroxynitrate H 3NO 4 Orthonitric acid NO3− 4 Orthonitrate +3 HNO 2 Nitrous acid NO−...

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List of compounds with carbon number 1

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2264-21-3 CF3NO trifluoronitrosomethane 334-99-6 CF3NO4 trifluoromethyl peroxynitrate 50311-48-3 CF4 carbon tetrafluoride 75-73-0 CF4O trifluoromethyl hypofluorite...

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Antimicrobial photodynamic therapy

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hypobromite, while NaNO2 reacts with singlet oxygen to form unstable peroxynitrate. NaN3 quenches singlet oxygen so it can only react by electron transfer...

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