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Pentamethylcyclopentadienyl rhodium dichloride dimer information


Pentamethylcyclopentadienyl rhodium dichloride dimer
Cp(star)RhCl2 dimer-2
Cp(star)RhCl2 dimer-powder
Names
IUPAC name
Di-μ-chloro-bis[chloro(pentamethylcyclopentadienyl)rhodium(III)]
Other names
Dichloro(pentamethylcyclopentadienyl)rhodium(III)
Identifiers
CAS Number
  • 12354-85-7  checkY
3D model (JSmol)
  • Interactive image
ChemSpider
  • 26583494
PubChem CID
  • 16212157
InChI
  • InChI=1S/2C10H15.4ClH.2Rh/c2*1-6-7(2)9(4)10(5)8(6)3;;;;;;/h2*1-5H3;4*1H;;/q;;;;;;2*+2/p-4
    Key: QNIVKTTWBMFSBR-UHFFFAOYSA-J
SMILES
  • c1(C)=c(C)c(C)=c(C)c1(C)[Rh](Cl)(Cl1)Cl[Rh](Cl)1C1(C)C(C)=C(C)C(C)=C1C
Properties
Chemical formula
 C20H30Cl4Rh2
Molar mass 618.07 g·mol−1
Appearance red solid
Solubility in water
 dichloromethane, chloroform
Hazards
GHS labelling:
Pictograms
 GHS07: Exclamation markGHS08: Health hazard
Signal word
 Danger
Hazard statements
 H302, H312, H315, H319, H332, H334, H335
Precautionary statements
 P261, P264, P270, P271, P280, P285, P301+P312, P302+P352, P304+P312, P304+P340, P304+P341, P305+P351+P338, P312, P321, P322, P330, P332+P313, P337+P313, P342+P311, P362, P363, P403+P233, P405, P501
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references

Pentamethylcyclopentadienyl rhodium dichloride dimer is an organometallic compound with the formula [(C5(CH3)5RhCl2)]2, commonly abbreviated [Cp*RhCl2]2 This dark red air-stable diamagnetic solid is a reagent in organometallic chemistry.[1]

  1. ^ Cite error: The named reference Mailtlis was invoked but never defined (see the help page).

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Pentamethylcyclopentadienyl rhodium dichloride dimer

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organoiridium(III) compounds are generated from pentamethylcyclopentadienyl iridium dichloride dimer. Many of derivatives feature kinetically inert cyclometalated...

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