In chemistry, an oxocarbon or oxide of carbon is a chemical compound consisting only of carbon and oxygen.[1][2] The simplest and most common oxocarbons are carbon monoxide (CO) and carbon dioxide (CO2). Many other stable (practically if not thermodynamically) or metastable oxides of carbon are known, but they are rarely encountered, such as carbon suboxide (C3O2 or O=C=C=C=O) and mellitic anhydride (C12O9).
CO Carbon monoxide
CO2 Carbon dioxide
C3O2 Carbon suboxide
C12O9 Mellitic anhydride
Many other oxides are known today, most of them synthesized since the 1960s. Some of these new oxides are stable at room temperature. Some are metastable or stable only at very low temperatures, but decompose to simpler oxocarbons when warmed. Many are inherently unstable and can be observed only momentarily as intermediates in chemical reactions or are so reactive that they exist only in gas phase or have only been detected by matrix isolation.
Graphene oxide and other stable polymeric carbon oxides with unbounded molecular structures exist.[3][4]
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IUPAC, Compendium of Chemical Terminology, 2nd ed. (the "Gold Book") (1997). Online corrected version: (1995) "Oxocarbons". doi:10.1351/goldbook.O04375
^West, R. (ed.) (1980), Oxocarbons. Academic Press, New York.
^Cite error: The named reference hummers was invoked but never defined (see the help page).
^Cite error: The named reference snow was invoked but never defined (see the help page).
chemistry, an oxocarbon or oxide of carbon is a chemical compound consisting only of carbon and oxygen. The simplest and most common oxocarbons are carbon...
In chemistry, an oxocarbon anion is a negative ion consisting solely of carbon and oxygen atoms, and therefore having the general formula C xOn− y for...
electrosynthesis of H2O2 in aqueous media. The carbonate ion is the simplest oxocarbon anion. It consists of one carbon atom surrounded by three oxygen atoms...
two of myriad carbonylation processes. Carbon monoxide is the simplest oxocarbon and is isoelectronic with other triply-bonded diatomic species possessing...
encountered in everyday life. It is classified as a carbene, cumulene and an oxocarbon. Dicarbon monoxide is a product of the photolysis of carbon suboxide:...
Carbon trioxide (CO3) is an unstable oxide of carbon (an oxocarbon). The possible isomers of carbon trioxide include ones with molecular symmetry point...
alcohol. In theory it could lose four protons to give the hypothetical oxocarbon anion orthocarbonate CO4−4, and is therefore considered an oxoacid of...
hydrogensquarate anion is the divalent squarate anion C4O2−4. This is one of the oxocarbon anions, which consist only of carbon and oxygen. Squaric acid is a reagent...
over into organometallic chemistry. There are many oxides of carbon (oxocarbons), of which the most common are carbon dioxide (CO2) and carbon monoxide...
besides carbon and oxygen, mellitic anhydride is an oxide of carbon (oxocarbon), and, along with CO2, CO, and C3O2, is one of the only four that are...
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nickel tetracarbonyl), mellitic anhydride (C12O9), and other exotic oxocarbons are also considered inorganic by some authorities.[citation needed] Nickel...
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the fivefold ketone of cyclopentane. It would be an oxide of carbon (an oxocarbon), indeed a pentamer of carbon monoxide. As of 2000, the compound had yet...
((N≡C−)2C=)3(C5O2)2−. It is one of the pseudo-oxocarbon anions, as it can be described as a derivative of the croconate oxocarbon anion C 5O2− 5 through the replacement...
it a cumulene. It is one of the stable members of the series of linear oxocarbons O=Cn=O, which also includes carbon dioxide (CO2) and pentacarbon dioxide...
or the two-fold ketone of ethylene oxide. It is an oxide of carbon (an oxocarbon). The simple compound apparently has yet to be observed (as of 2009)....
Carbon compounds#Carbon halides Carbon compounds#Carbon-oxygen compounds Oxocarbon Greenwood, Norman N.; Earnshaw, Alan (1997). Chemistry of the Elements...
C6O6, the sixfold ketone of cyclohexane. It is an oxide of carbon (an oxocarbon), a hexamer of carbon monoxide. The compound is expected to be highly...
chemistry, while silicate minerals have a structural complexity unseen in oxocarbons. Silicon tends to resemble germanium far more than it does carbon, and...
organic compound with the formula C4O6. It is an oxide of carbon (an oxocarbon), which can be viewed as the fourfold ketone of dioxane. It can also be...
trioxoglutarate anion, C 5O2− 7 or −O−(C=O)5−O−. This would be one of the oxocarbon anions, which consist solely of carbon and oxygen. The name would also...
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