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Oxocarbon information


In chemistry, an oxocarbon or oxide of carbon is a chemical compound consisting only of carbon and oxygen.[1][2] The simplest and most common oxocarbons are carbon monoxide (CO) and carbon dioxide (CO2). Many other stable (practically if not thermodynamically) or metastable oxides of carbon are known, but they are rarely encountered, such as carbon suboxide (C3O2 or O=C=C=C=O) and mellitic anhydride (C12O9).

       
CO
Carbon
monoxide
CO2
Carbon
dioxide
C3O2
Carbon
suboxide
C12O9
Mellitic
anhydride

Many other oxides are known today, most of them synthesized since the 1960s. Some of these new oxides are stable at room temperature. Some are metastable or stable only at very low temperatures, but decompose to simpler oxocarbons when warmed. Many are inherently unstable and can be observed only momentarily as intermediates in chemical reactions or are so reactive that they exist only in gas phase or have only been detected by matrix isolation.

Graphene oxide and other stable polymeric carbon oxides with unbounded molecular structures exist.[3][4]

  1. ^ IUPAC, Compendium of Chemical Terminology, 2nd ed. (the "Gold Book") (1997). Online corrected version: (1995) "Oxocarbons". doi:10.1351/goldbook.O04375
  2. ^ West, R. (ed.) (1980), Oxocarbons. Academic Press, New York.
  3. ^ Cite error: The named reference hummers was invoked but never defined (see the help page).
  4. ^ Cite error: The named reference snow was invoked but never defined (see the help page).

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Oxocarbon

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chemistry, an oxocarbon or oxide of carbon is a chemical compound consisting only of carbon and oxygen. The simplest and most common oxocarbons are carbon...

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Oxocarbon anion

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In chemistry, an oxocarbon anion is a negative ion consisting solely of carbon and oxygen atoms, and therefore having the general formula C xOn− y for...

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Carbon dioxide

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Hafnium dioxide Cerium dioxide Thorium dioxide Related carbon oxides See Oxocarbon Related compounds Carbonic acid Carbonyl sulfide Carbonyl selenide Supplementary...

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Carbonate

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electrosynthesis of H2O2 in aqueous media. The carbonate ion is the simplest oxocarbon anion. It consists of one carbon atom surrounded by three oxygen atoms...

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Carbon monoxide

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two of myriad carbonylation processes. Carbon monoxide is the simplest oxocarbon and is isoelectronic with other triply-bonded diatomic species possessing...

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Dicarbon monoxide

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encountered in everyday life. It is classified as a carbene, cumulene and an oxocarbon. Dicarbon monoxide is a product of the photolysis of carbon suboxide:...

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Carbon trioxide

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Carbon trioxide (CO3) is an unstable oxide of carbon (an oxocarbon). The possible isomers of carbon trioxide include ones with molecular symmetry point...

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Orthocarbonic acid

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alcohol. In theory it could lose four protons to give the hypothetical oxocarbon anion orthocarbonate CO4−4, and is therefore considered an oxoacid of...

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Squaric acid

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hydrogensquarate anion is the divalent squarate anion C4O2−4. This is one of the oxocarbon anions, which consist only of carbon and oxygen. Squaric acid is a reagent...

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Carbon compounds

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over into organometallic chemistry. There are many oxides of carbon (oxocarbons), of which the most common are carbon dioxide (CO2) and carbon monoxide...

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Mellitic anhydride

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besides carbon and oxygen, mellitic anhydride is an oxide of carbon (oxocarbon), and, along with CO2, CO, and C3O2, is one of the only four that are...

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Pentacarbon dioxide

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officially penta-1,2,3,4-tetraene-1,5-dione, is an oxide of carbon (an oxocarbon) with formula C5O2 or O=C=C=C=C=C=O. The compound was described in 1988...

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Ethylene dione

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compound with the formula C2O2 or O=C=C=O. It is an oxide of carbon (an oxocarbon), and can be described as the carbon-carbon covalent dimer of carbon monoxide...

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Organic compound

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nickel tetracarbonyl), mellitic anhydride (C12O9), and other exotic oxocarbons are also considered inorganic by some authorities.[citation needed] Nickel...

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Tricarbon monoxide

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Tricarbon monoxide C3O is a reactive radical oxocarbon molecule found in space, and which can be made as a transient substance in the laboratory. It can...

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Cyclopentanepentone

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the fivefold ketone of cyclopentane. It would be an oxide of carbon (an oxocarbon), indeed a pentamer of carbon monoxide. As of 2000, the compound had yet...

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Croconate blue

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((N≡C−)2C=)3(C5O2)2−. It is one of the pseudo-oxocarbon anions, as it can be described as a derivative of the croconate oxocarbon anion C 5O2− 5 through the replacement...

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Carbon suboxide

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it a cumulene. It is one of the stable members of the series of linear oxocarbons O=Cn=O, which also includes carbon dioxide (CO2) and pentacarbon dioxide...

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Oxalic anhydride

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or the two-fold ketone of ethylene oxide. It is an oxide of carbon (an oxocarbon). The simple compound apparently has yet to be observed (as of 2009)....

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Carbon oxohalide

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Carbon compounds#Carbon halides Carbon compounds#Carbon-oxygen compounds Oxocarbon Greenwood, Norman N.; Earnshaw, Alan (1997). Chemistry of the Elements...

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Cyclohexanehexone

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C6O6, the sixfold ketone of cyclohexane. It is an oxide of carbon (an oxocarbon), a hexamer of carbon monoxide. The compound is expected to be highly...

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Silicon

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chemistry, while silicate minerals have a structural complexity unseen in oxocarbons. Silicon tends to resemble germanium far more than it does carbon, and...

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Dioxane tetraketone

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organic compound with the formula C4O6. It is an oxide of carbon (an oxocarbon), which can be viewed as the fourfold ketone of dioxane. It can also be...

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Trioxoglutaric acid

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trioxoglutarate anion, C 5O2− 7 or −O−(C=O)5−O−. This would be one of the oxocarbon anions, which consist solely of carbon and oxygen. The name would also...

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Carbon tetroxide

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Carbon tetroxide or Oxygen carbonate (in its C2v isomer) is a highly unstable oxide of carbon with formula CO 4. It was proposed as an intermediate in...

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Peroxycarbonate

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oxidocarbonate) or percarbonate is a divalent anion with formula CO2− 4. It is an oxocarbon anion that consists solely of carbon and oxygen. It would be the anion...

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Acetylenedicarboxylic acid

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dianion C4O2−4, which consists only of carbon and oxygen, making it an oxocarbon anion. Partial ionization yields the monovalent hydrogen acetylenedicarboxylate...

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