Global InformationNeopolarogram information
The term neopolarogram refers to mathematical derivatives of polarograms or cyclic voltammograms that in effect deconvolute diffusion and electrochemical kinetics. This is achieved by analog or digital implementations of fractional calculus.[1] The implementation of fractional derivative calculations by means of numerical methods is straight forward. The G1- (Grünwald–Letnikov derivative) and the RL0-algorithms (Riemann–Liouville integral) are recursive methods to implement a numerical calculation of fractional differintegrals. Yet differintegrals are faster to compute in discrete fourier space using FFT.[2]
- ^ Keith Oldham, Jerome Spanier; The Fractional Calculus: Theory and Applications of Differentiation and Integration to Arbitrary Order (Dover Books on Mathematics)
- ^ Jun-Sheng Yu, Zu-Xun Zhanga; "Differentiation, semidifferentiation and semi-integration of a digital signals based on Fourier transformations"; Journal of Electroanalytical Chemistry; Volume 403, Issues 1-2, 21 February 1996, Pages 1-9; doi:10.1016/0022-0728(95)04328-4