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Mottramite information


Mottramite
General
CategoryVanadate minerals
Formula
(repeating unit)
PbCu(VO4)(OH)
IMA symbolMott[1]
Strunz classification8.BH.40
Dana classification41.5.2.2
Crystal systemOrthorhombic
Crystal classDipyramidal (mmm)
H-M symbol: (2/m 2/m 2/m)
Space groupPnma
Unit cella = 7.68 Å, b = 9.27 Å,
c = 6.03 Å; Z = 4
Identification
Formula mass402.69 g/mol[2]
ColourGrass-green, olive-green, yellow-green, siskin-green, blackish brown, nearly black
Crystal habitEncrustations, aggregates of plume-like forms and radial crystals[2]
CleavageNone observed
FractureIrregular/uneven, sub-conchoidal
TenacityBrittle
Mohs scale hardness3 – 3+12
LustreGreasy
StreakYellowish green
DiaphaneityTransparent, opaque
Specific gravity5.9
Optical propertiesUsually biaxial (−) rarely biaxial (+)
Refractive indexnα = 2.170(2) nβ = 2.260(2) nγ = 2.320(2)
Birefringenceδ = 0.150
PleochroismVisible X=Y= canary yellow to greenish yellow, Z= brownish yellow
2V angleMeasured: 73° , calculated: 46°
DispersionStrong r > v rarely r < v
SolubilityReadily soluble in acids[3]
Common impuritiesZinc
References[2][3][4][5][6]

Mottramite is an orthorhombic anhydrous vanadate hydroxide mineral, PbCu(VO4)(OH), at the copper end of the descloizite subgroup. It was formerly called cuprodescloizite or psittacinite (this mineral characterized in 1868 by Frederick Augustus Genth). Duhamelite is a calcium- and bismuth-bearing variety of mottramite, typically with acicular habit.[3]

Mottramite is a member of the adelite-descloizite group.[3] Mottramite, which is a copper rich member, forms a series with descloizite, which is a zinc rich member.[3][5] These two minerals usually contain significant percentages of both copper and zinc and are seldom pure. Mottramite also forms a series with duftite.[3]

It was discovered in 1876[3] and named for the locality, Mottram St Andrew, Cheshire, England, where ore was stockpiled, although it was probably mined from Pim Hill Mine, Shrewsbury, Shropshire, England.[3][5][7]

  1. ^ Warr, L.N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine. 85 (3): 291–320. Bibcode:2021MinM...85..291W. doi:10.1180/mgm.2021.43. S2CID 235729616.
  2. ^ a b c Mottramite data on Webmneral
  3. ^ a b c d e f g h Mottramite on Mindat.org
  4. ^ Gaines et al (1997) Dana’s New Mineralogy, Eighth Edition. Wiley
  5. ^ a b c Mottramite in the Handbook of Mineralogy
  6. ^ Mineralienatlas
  7. ^ Kingsbury and Hartley (1956). New occurrences of vanadium minerals (mottramite, descloizite, (discredited) and vanadinite) in the Caldbeck area of Cumberland. Mineralogical Magazine 31:289

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